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MODULATING CH 3 NH 3 PbI 3 PEROVSKITE CRYSTALLIZATION BEHAVIOR THROUGH PRECURSOR CONCENTRATION
KUNWU FU,SUBODH MHAISALKAR,SWEE SIEN LIM,PABLO P. BOIX,NRIPAN MATHEWS,YANAN FANG,LYDIA H. WONG,TZE CHIEN SUM 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.5
Perovskite-based photovoltaic devices have recently achieved impressively high e±ciencies be-yond 15% and gained great interest. We show here the formation of perovskite cluster overlayerstructures which consist of individual perovskite grains on top of mesoporous TiO 2 ¯lms, coex-isting with the randomly distributed nanocrystals within the ¯lms. Perovskite solution concen-tration was found to play an important role in modulating the perovskite crystallization andcluster overlayer formation process. Absorbance increase in visible wavelength range and shift ofphotoluminescence (PL) responses of perovskite ¯lms due to the e®ect of precursor concentrationchange were observed and investigated in detail. The crystallographic analysis of theCH 3 NH 3 PbI 3 ¯lms shows a gradual decrease of the perovskite lattice parameters and shrinkage ofunit volume as precursor solution concentration increases, which is correlated to the changes ofoptical properties. Finally, perovskite-based solar cell device performance was enhanced at higherprecursor concentration.