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MoS2 FULLERENE-LIKE NANOPARTICLES AND NANOTUBES USING GAS-PHASE REACTION WITH MoCl5
F. L. DEEPAK,MAYA BAR-SADAN,RESHEF TENNE,ALEXANDER MARGOLIN,INNA WIESEL,RONIT POPOVITZ-BIRO 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2006 NANO Vol.1 No.2
Inorganic fullerene-like (IF) nanoparticles of MoS2 were synthesized using gas-phase reaction starting from MoCl5 and H2S. The IF-MoS2 nanoparticles are spherical and in some cases faceted with diameters in general ranging between 20 and 80 nm. The IF-MoS2 nanoparticles have large hollow cores, filled in some cases with amorphous material. Various parameters have been investigated to understand the growth and formation of the IF-MoS2 nanoparticles. The parameters that have been studied include flow rates of the various carrier gases, temperature at which the reaction was carried out, time of the reaction and heating of the precursor material. The best set of conditions wherein maximum yields of the IF-MoS2 nanoparticles are obtained have been identified. Additionally, annealing the as-obtained samples or heating them in a mixture of H2 along with H2S improves the crystallinity and reduces the amorphous material filling in the core. Apart from the fullerene-like nanoparticles under certain experimental conditions nanotubes of MoS2 have also been obtained nonetheless in small yields.
Synthesis and Characterization of Pb@GaS Core–Shell Fullerene-Like Nanoparticles and Nanotubes
Olga Brontvein,Lothar Houben,RONIT POPOVITZ-BIRO,Moshe Levy,Daniel Feuermann,RESHEF TENNE,Jeffrey M. Gordon 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.3
New types of core–shell nanoparticles are reported: Pb@GaS fullerene-like and nanotubular structures, achieved via the continuously high reactor temperatures and ultra-hot stronggradient annealing environments created by highly concentrated sunlight. Structural and chemical characterizations suggest a formation mechanism where vaporized Pb condenses into nanoparticles that are stabilized as they become covered by molten GaS, the ensuing crystallization of which creates the outer layers. Hollow-core GaS fullerene-like nanoparticles and nanotubes were also observed among the products, demonstrating that a single solar procedure can generate a variety of core–shell and hollow nanostructures. The proposed formation mechanisms can account for their relative abundance and the characterization data.