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Balasubramanian Viswanathan,Raman Ganesan 한국화학공학회 2005 Korean Journal of Chemical Engineering Vol.22 No.1
Bis(ethylenediamine) copper(II) complex was encapsulated in NaY, KL, Na and NaZSM-5 zeolite. Theredox properties of metal complexes in neat and encapsulated state were studied by cyclic voltammetry. The redoxpotential of metal complex is altered towards negative value upon encapsulation in various zeolites. This may be dueto axial interaction with various zeolite matrix. The redox properties of biological systems are also altered (cytochrome-C, and Vitamin-B12) when they are imobilized on NaAlMCM-41 materials. The coper ethylenediamine complexin constrained environment shows higher activity for the oxidation of dimethyl sulfide compared to that of neat complex.