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Poly(o-anisidine) on brass: Synthesis and corrosion behavior
Ali Tuncay Ozyilmaz,Gul Ozyilmaz,Ercan Y lmaz,Nureddin Çolak 한국화학공학회 2008 Korean Journal of Chemical Engineering Vol.25 No.4
The electrochemical synthesis of poly(o-anisidine) (POA) was achieved on brass (CuZn) electrode by applying two scan rates (50 and 20 mVs−1). The synthesized polymer films were strongly adherent and homogeneous in both cases. Their corrosion performance was investigated by AC impedance spectroscopy (EIS) technique, anodic polarization plots and open circuit potential-time curves, in 3.5% NaCl solution. It was clearly seen that poly(o-anisidine) films provided a significant physical protection for longer exposure time. It was shown that polymer film coated at high scan rate (CuZn/POA-H) exhibited better barrier property against the attack of corrosive agents when compared with polymer film obtained at low scan rate (CuZn/POA-L). It was found out that poly(o-anisidine) film synthesized at high scan rate caused a significant increase in corrosion resistance by its catalytic behavior on formation of protective oxide layers on the surface in longer time