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Victoria Volkis,Sinai Aharonovich,Moris S. Eisen 한국고분자학회 2010 Macromolecular Research Vol.18 No.10
A new epimerization mechanism was introduced for the polymerization of propylene obtained by octahedral benzamidinate complexes. Deuterium labeling showed that deuterium is transferred from a methyne to a methylene position in the polymer inducing a stereoerror and an elastic material. In addition, two active species are formed during the polymerization of propylene promoted by the octahedral bis(benzamidinate) titanium dialkyl complexes.