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Xingwang Zhou,Jia Zhou,Yongwei Yu,Jiangquan Ma,Xueni Sun,Lanmei Hu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.10
In this research, a series of catalysts based on MoSe2 were synthesized by the hydrothermal method and used for the catalytic hydrogenation of alkali lignin for the first time. For 4 wt.% NiSe2/MoSe2 catalyst, at 290 ℃, under 2MPa H2 pressure for 1.5 h, the conversion of alkali lignin and the yield of bio-oil reached 96.47% and 93.68%, respectively. In addition, the composition of the product (bio-oil) was analyzed via Fourier transform infrared (FTIR) spectrometry, gas chromatography-mass spectrometry (GC-MS) spectra, and proton nuclear magnetic resonance (1HNMR) spectra. Finally, our study demonstrated that those MoSe2-based composite catalysts can effectively degrade the biomass into bio-oil containing valuable chemical products.