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      • Electrospun carbon nanofiber-carbon nanotubes coated polyaniline composites with improved electrochemical properties for supercapacitors

        Agyemang, Frank Ofori,Tomboc, Gracita M.,Kwofie, Samuel,Kim, Hern Elsevier 2018 ELECTROCHIMICA ACTA Vol.259 No.-

        <P><B>Abstract</B></P> <P>The carbon nanofiber-carbon nanotube (CNF-CNT) composites were fabricated by simple electrospinning and carbonization of polyacrylonitrile (PAN)-CNT solution prepared by first sonicating and stirring the CNT in N, N-dimethylformamide (DMF) as solvent. Aniline monomer was then coated on the composite materials via in situ chemical polymerization to form CNF-CNT-PANI composite. The as-prepared samples were then characterized. Importantly, the dispersed CNTs in the CNF-CNT composites were crucial for the CNF-CNTs acting as supports for the CNF-CNT-PANI composites to attain high electrochemical properties. The composite electrode material is found to be used as effective electrode material for supercapacitors with specific capacitance as high as 1119 F g<SUP>−1</SUP>at 1 A g<SUP>−1</SUP> compared to the bare CNF film with a specific capacitance of 278 F g<SUP>−1</SUP>. The composite electrode displaced excellent cyclic stability with retention of 98% even after 2000 cycles at a current density of 10 A g<SUP>−1</SUP>.</P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

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        Continuous peripheral nerve blocks (CPNBs) compared to thoracic epidurals or multimodal analgesia for midline laparotomy: a systematic review and meta-analysis

        Bailey Jonathan G,Morgan Catherine,Christie Russell,Ke Janny,Kwofie Kwesi,Uppal Vishal 대한마취통증의학회 2021 Korean Journal of Anesthesiology Vol.74 No.5

        Background: Continuous peripheral nerve blocks (CPNBs) have been investigated to control pain for abdominal surgery via midline laparotomy while avoiding the adverse events of opioid or epidural analgesia. The review compiles the evidence comparing CPNBs to multimodal and epidural analgesia. Methods: We conducted a systematic review using broad search terms in MEDLINE, Embase, Cochrane. Primary outcomes were pain scores and cumulative opioid consumption at 48 hours. Secondary outcomes were length of stay and postoperative nausea and vomiting (PONV). We rated the quality of the evidence using Cochrane and GRADE recommendations. The results were synthesized by meta-analysis using Revman. Results: Our final selection included 26 studies (1,646 patients). There was no statistically significant difference in pain control comparing CPNBs to either multimodal or epidural analgesia (low quality evidence). Less opioids were consumed when receiving epidural analgesia than CPNBs (mean difference [MD]: –16.13, 95% CI [–32.36, 0.10]), low quality evidence) and less when receiving CPNBs than multimodal analgesia (MD: –31.52, 95% CI [–42.81, –20.22], low quality evidence). The length of hospital stay was shorter when receiving epidural analgesia than CPNBs (MD: –0.78 days, 95% CI [–1.29, –0.27], low quality evidence) and shorter when receiving CPNBs than multimodal analgesia (MD: –1.41 days, 95% CI [–2.45, –0.36], low quality evidence). There was no statistically significant difference in PONV comparing CPNBs to multimodal (high quality evidence) or epidural analgesia (moderate quality evidence). Conclusions: CPNBs should be considered a viable alternative to epidural analgesia when contraindications to epidural placement exist for patients undergoing midline laparotomies.

      • Heavy metal assessment of marine sediment in selected coastal districts of the Western Region, Ghana

        Kuranchie-Mensah, Harriet,Osei, Juliet,Atiemo, Sampson M.,Nyarko, Benjamin J.B.,Osae, Shiloh K.,Laar, Cynthia,Ackah, Michael,Buah-Kwofie, Archibold,Blankson-Arthur, Sara,Adeti, Prince J. Techno-Press 2013 Advances in environmental research Vol.2 No.2

        A preliminary investigation to establish the status of contamination of trace metals in the Western coast of Ghana was conducted prior to the commercial production of crude oil in the area. The study revealed the presence of heavy metals such as Pb (4.00-79.64 mg/kg), As (8.81-236 mg/kg), Cu (12.86-108.06 mg/kg), V (28.07-953.32 mg/kg), Zn (7.08-264.25 mg/kg), Cr (101.69-1366.62 mg/kg), Ni (42.41-451.43 mg/kg), Mn (16.77-1890.45mg/kg), Br (7.66-142.78 mg/kg), Ti (542.03-19960 mg/kg) and Fe (7472.88-97120 mg/kg) at six sites sampled along the coast. With the exception of Ti and Fe which showed no variation in metal concentration, the rest of the metals varied significantly among the sampled locations. Potential ecological risk of metals particularly of Co, As and Br which exhibited extreme enrichment of the sediments indicates considerable metal pollution in the studied areas. The degree of contamination is of particular concern especially to benthic biota that inhabit this environment for survival.

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