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Phase equilibria and thermodynamic properties in the o-dichlorobenzene - mdichlorobenzene system
Konstantin Samukov,Aleksey Maksimov,Ekaterina Belova,Mikhail Bubenchikov,Irina Uspenskaya 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.12
Rankine cycle is widely used in industry to convert heat to work using a working fluid. A mixture of oandm-isomers of dichlorobenzene can act efficiently as a working fluid in the cycle. An equation of state (EoS) approachwas chosen to model vapor-liquid equilibria and phase properties in the system. The best results were achieved withTsai-Chen EoS. Experimental measurements of volumetric properties of mixtures and solid-liquid equilibria were performed. These data were correctly predicted within the ideal assumption. An enthalpy-pressure diagram for the odichlorobenzene- m-dichlorobenzene system was calculated using the resulting EoS.