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Huanhuan Xu,Lihe Yan,Jinhai Si,Yanmin Xu,Xun Hou 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.5
Zinc oxide (ZnO) nanoparticles (NPs) are synthesized by one-step femtosecond laser ablation of zinc powders in n-methyl pyrrolidone (NMP) at room temperature. The as-prepared ZnO NPs are fairly stable, water-soluble and have abundant surface functional groups resulting in a strong fluorescence in the visible region. By further annealing the ZnO NPs in the reacting solvent up to 120 ℃, the photoluminescence (PL) intensity of material can be significantly enhanced. Besides, the PL of ZnO NPs can change from blue to green by controlling the annealing temperature. The products exhibit excellent temperature sensing with high temperature sensitivity and a 1.3% change per ℃ response over a linear temperature sensing range (6–84 ℃) in aqueous buffer, which matches well with the physiologically relevant temperatures. Hence, the ZnO nanoparticle system can serve as a promising candidate for practical fluorescent temperatures nanosensors which can be used for accurate temperature monitoring within biological systems.