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      • KCI등재

        Simulation of the Grain Size Effect in Gas-Sensitive SnO2 Thin Films Using the Oxygen Vacancy Gradient Distribution Model

        Jianqiao Liu,Zhaoxia Zhai,Guohua Jin,Yuan Li,Faheema Fairuj Monica,Xuesong Liu 대한금속·재료학회 2015 ELECTRONIC MATERIALS LETTERS Vol.11 No.1

        The model of gradient-distributed oxygen vacancies is utilized in simulatingthe grain size effects of gas-sensitive SnO2 thin films. The distribution profileof oxygen vacancies has a grain size effect and the profile gradient correlatespositively with the radius of the grains. The simulation results show that thegrain size is a fundamental factor dominating the gas-sensing properties ofthin films. The potential barrier height and resistivity have significant grainsize effects when m is between 0.1 and 0.5 nm−1. The size effects on sensorresponse to stimulant gases can be enhanced by increasing the value of m orthe absolute value of α. Two expressions are used to simulate the grain sizeeffect of the sensor response. The expressions act similarly when α < 0.2. The simplified response provides a neat function to quantitatively explain thesensor performance on gases with low partial pressure. Although the accurate response is complicated, it is applicable to theentire concentration range. A small power-law exponent n is calculated from the accurate response expression when a high gasconcentration is employed, illustrating a “saturation effect” of the response.

      • KCI등재

        Numeral Description of Grain Size Effects of Tin Oxide Gas-Sensitive Elements and Evaluation of Depletion Layer Width

        Jianqiao Liu,Guohua Jin,Zhaoxia Zhai,Faheema Fairuj Monica,Xuesong Liu 대한금속·재료학회 2015 ELECTRONIC MATERIALS LETTERS Vol.11 No.3

        The grain size effects on tin oxide gas-sensitive elements are numerically described by the model of gradient-distributed oxygen vacancies, which extends the receptor function of semiconductors to the condition of inhomogeneous donor density in grains. The sensor resistance and the response to the reducing gas are formulated as functions of the grain size and the depletion layer width. The simulations show good agreement with the experimental results. The depletion layer width is estimated as 4 nm for the undoped SnO2 element, whereas the values are 2 and 7 nm for Sb-doped and Al-doped samples, respectively. The results are experimentally verified by the donor-doped SnO2 thin films, the depletion layer widths of which are evaluated on the basis of the correlation between the electrical resistance and the Sb-doping amount. The location of the Fermi level is found to be a crucial factor that dominates the evaluation results.

      • KCI등재

        Fascia Suture Technique Is a Simple Approach to Reduce Postmastectomy Seroma Formation

        Yizi Cong,Jianqiao Cao,Guangdong Qiao,Song Zhang,Xinjie Liu,Xiaoming Fang,Haidong Zou,Shiguang Zhu 한국유방암학회 2020 Journal of breast cancer Vol.23 No.5

        Purpose: Seroma formation is a common complication in breast cancer patients undergoing mastectomy, and it negatively affects patient recovery after surgery. The present study aimed to evaluate a simple method using fascia suture technique to fix the flap and reduce the incidence of seroma. Methods: A single-center, prospective, randomized controlled trial was carried out among 160 patients who had undergone mastectomy from May 2018 to September 2019. All patients were randomly divided into the fascia suture group (n = 80) or control group (n = 80) and were followed up for at least 3 months for the assessment of immediate and late complications after surgery. Results: No significant differences were observed between the 2 groups with regard to the basic characteristics. Duration of surgery in the fascia suture group was longer by about 6 minutes compared with that in the control group (114.93 ± 13.67 minutes vs. 108.81 ± 15.20 minutes, p = 0.008). The fascia suture group had a shorter duration of drain placement (10.99 ± 3.26 days vs. 13.85 ± 5.37 days, p < 0.001), a smaller volume of the total drainage (460.95 ± 242.92 mL vs. 574.83 ± 285.23 mL, p = 0.007), and the first 3-day drainage (224.96 ± 101.01 mL vs. 272.3 ± 115.47 mL, p = 0.006), compared with the control group. The incidence of seroma formation (G2 or G3) was significantly lower in the fascia suture group compared with the control group (28.8% vs. 12.5%, p = 0.033). Besides, there was no statistical difference between the 2 groups in the assessment of other complications, including postoperative pain, hematoma, surgical site infections, flap necrosis, and skin dimpling (all p > 0.050). Conclusion: The fascia suture technique is a simple and effective method for reducing seroma formation and should be used to prevent seroma formation after mastectomy.

      • KCI등재

        Catalytic performance of CuCl2-modified V2O5-WO3/TiO2 catalyst for Hg0 oxidation in simulated flue gas

        Chuanmin Chen,Wenbo Jia,Songtao Liu,Yue Cao,Bing Zhao,Jianqiao Wang 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.3

        CuCl2-SCR catalysts prepared by an improved impregnation method were studied to evaluate the catalytic performance for gaseous elemental mercury (Hg0) oxidation in simulated flue gas. Hg0 oxidation activity of commercial SCR catalyst was significantly improved by the introduction of CuCl2. Nitrogen adsorption, XRD, XRF and XPS were used to characterize the catalysts. The results indicated that CuCl2 was well loaded and highly dispersed on the catalyst surface, and that CuCl2 played an important role for Hg0 catalytic oxidation. The effects of individual flue gas components on Hg0 oxidation were also investigated over CuCl2-SCR catalyst at 350 oC. The co-presence of NO and NH3 remarkably inhibited Hg0 oxidation, while this inhibiting effect was gradually scavenged with the decrease of GHSV. Further study revealed the possibility of simultaneous removal of Hg0 and NO over CuCl2-SCR catalyst in simulated flue gas. The mechanism of Hg0 oxidation was also investigated.

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