http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
XIAOYU ZHANG,JIANLI HUA,JINXIANG HE,WENJUN WU,HANS AGREN,XIN LI,FULING GUO 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.5
In this paper, we have designed and synthesized four bithiazole-bridged sensitizers (BT-T2,TBT-T2, BT-T3 and TBT-T3) with triphenylamine and indoline as the donor segment andapplied them to dye-sensitized solar cells (DSSCs). For triphenylamine-based sensitizers as BT-T2 and TBT-T2, adding one thiophene unit between triphenylamine donor and bithiazolemoiety not only led to bathochromic shift of the maximum absorption and increase of molarextinction coe±cient, but also enhanced the photovoltaic conversion e±ciency from 7.12% ofBT-T2 to 7.51% of TBT-T2. But for indoline-based sensitizers as BT-T3 and TBT-T3,adding one thiophene unit between indoline donor and bithiazole moiety resulted in hypochro-matic shift instead of bathochromic shift. We employed the density functional theory (DFT)calculations to further investigate the in°uence of the thiophene unit on their optical and elec-tronic properties and photovoltaic performance of corresponding DSSC devices. Given theresults, a reasonable explanation is the introduction of thiophene unit suppressed the intramo-lecular charge transfer and charge separation in the conjugation system of indoline-based sen-sitizer, which led to the hypochromatic shift of the maximum absorption wavelength and ¯nallythe low Jsc . Since the Jsc dropped sharply from 15.26 mAcm? 2 to 4.52 mAcm? 2 , the photovoltaicconversion e±ciency decreased dramatically from 7.86% to 1.93%.