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- 저자 : Garcia-Garibay, Miguel A. (검색결과 3 건)
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Proteolytic System of Streptococcus thermophilus
( G. M. Rodriguez-serrano ),( M. Garcia-garibay ),( A. E. Cruz-guerrero ),( L. Gomez-ruiz ),( A. Ayala-nino ),( A. Castaneda-ovando ),( L. G. Gonzalez-olivares ) 한국미생물생명공학회(구 한국산업미생물학회) 2018 Journal of microbiology and biotechnology Vol.28 No.10
The growth of lactic acid bacteria (LAB) generates a high number of metabolites related to aromas and flavors in fermented dairy foods. These microbial proteases are involved in protein hydrolysis that produces necessary peptides for their growth and releases different molecules of interest, like bioactive peptides, during their activity. Each genus in particular has its own proteolytic system to hydrolyze the necessary proteins to meet its requirements. This review aims to highlight the differences between the proteolytic systems of Streptococcus thermophilus and other lactic acid bacteria (Lactococcus and Lactobacillus) since they are microorganisms that are frequently used in combination with other LAB in the elaboration of fermented dairy products. Based on genetic studies and in vitro and in vivo tests, the proteolytic system of Streptococcus thermophilus has been divided into three parts: 1) a serine proteinase linked to the cellular wall that is activated in the absence of glutamine and methionine; 2) the transport of peptides and oligopeptides, which are integrated in both the Dpp system and the Ami system, respectively; according to this, it is worth mentioning that the Ami system is able to transport peptides with up to 23 amino acids while the Opp system of Lactococcus or Lactobacillus transports chains with less than 13 amino acids; and finally, 3) peptide hydrolysis by intracellular peptidases, including a group of three exclusive of S. thermophilus capable of releasing either aromatic amino acids or peptides with aromatic amino acids.
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Photolysis of an asymmetrically substituted diazene in solution and in the crystalline state
Hoijemberg, Pablo Ariel,Karlen, Steven D.,Sanrame, Carlos Norberto,Aramendia, Pedro Francisco,Garcia-Garibay, Miguel Angel Korean Society of Photoscience 2009 Photochemical & photobiological sciences Vol.8 No.7
In this work we study the product distribution in the steady state photolysis of a diazene, (1-biphenyl-4-yl-1-methyl-ethyl)-tert-butyl diazene, and a ketone, 2,4-bis(biphenyl-4-yl)-2, 4-dimethyl-pentan-3-one, in the solid state and in solution. The two compounds yield 1-biphenyl-4-yl-1-methyl-ethyl (BME$^{\cdot}$) radicals upon photolysis. The ketone yields two units of this radical, whereas the diazene yields one BME$^{\cdot}$ and one tert-butyl radical. Product analysis of the two compounds in solution makes it possible to differentiate their origin from their corresponding geminate cages, and from the different encounter pairs in the case of the asymmetrically substituted diazene photolysis. In this way we obtain a complete reaction scenery for the diazene, a compound with interesting features as a radical photoinitiator and as a cage effect probe in fluid media. The reaction in cages containing two BME$^{\cdot}$ radicals shows a decrease by a factor of 4 in the ratio of combination to disproportionation products upon going from the solid to the liquid phase. On the contrary, the reaction in cages containing a BME$^{\cdot}$ and a tert-butyl radical shows a 30-fold increase in combination to disproportionation ratio in liquid compared to the crystal. We analyze the reasons for these differences considering the differences in the reactivity of the radicals and in cage rigidity.
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NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks
Morris, William,Stevens, Caitlin J.,Taylor, R. E.,Dybowski, C.,Yaghi, Omar M.,Garcia-Garibay, Miguel A. American Chemical Society 2012 The Journal of Physical Chemistry Part C Vol.116 No.24
<P>NMR relaxation studies and spectroscopic measurements of zeolitic imidazolate framework-8 (ZIF-8) are reported. The dominant nuclear spin–lattice relaxation (<I>T</I><SUB>1</SUB>) mechanism for ZIF-8 in air arises from atmospheric paramagnetic molecular oxygen. The <SUP>13</SUP>C <I>T</I><SUB>1</SUB> measurements indicate that the oxygen interacts primarily with the imidazolate ring rather than the methyl substituent. Similar relaxation behavior was also observed in a ZIF with an unsubstituted ring, ZIF-4. Single-crystal X-ray diffraction was used to provide data for the study of the thermal ellipsoids of ZIF-8 at variable temperatures from 100 to 298 K, which further confirmed the rigid nature of this ZIF framework. These results highlight a rigid ZIF framework and are in contrast with dynamic metal–organic frameworks based on benzenedicarboxylate linking groups, for which the relaxation reflects the dynamics of the benzenedicarboxylate moiety.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jpccck/2012/jpccck.2012.116.issue-24/jp303907p/production/images/medium/jp-2012-03907p_0003.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/jp303907p'>ACS Electronic Supporting Info</A></P>
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