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        Effects of aging on the phase transformation and sintering properties of coprecipitated Al₂O₃-ZrO₂ powders

        Chih-Cheng Chen,Hsing-I Hsiang,Fu-Su Yen 한양대학교 세라믹연구소 2008 Journal of Ceramic Processing Research Vol.9 No.1

        In this study, the effects of aging on the crystalline phases, crystallite sizes and sintering properties of coprecipitated Al₂O₃- ZrO₂ powders are investigated using thermogravimetry (TG), differential thermal analysis (DTA), X-ray diffractometry (XRD), dilatometry, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Coprecipitated Al₂O₃- ZrO₂ powder aging in the solution promoted the dissolution and reprecipitation process, which resulted in the boehmite structure subsequently transforming into bayerite. The densification and microstructural development of the coprecipitated Al₂O₃-ZrO₂ powders were dependent upon the aging time which shifted the θ→α-Al₂O₃ phase transformation to a higher temperature, lowered the crystallite growth rate, and prevented the occurrence of intragranular ZrO₂ particles during sintering. In this study, the effects of aging on the crystalline phases, crystallite sizes and sintering properties of coprecipitated Al₂O₃- ZrO₂ powders are investigated using thermogravimetry (TG), differential thermal analysis (DTA), X-ray diffractometry (XRD), dilatometry, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Coprecipitated Al₂O₃- ZrO₂ powder aging in the solution promoted the dissolution and reprecipitation process, which resulted in the boehmite structure subsequently transforming into bayerite. The densification and microstructural development of the coprecipitated Al₂O₃-ZrO₂ powders were dependent upon the aging time which shifted the θ→α-Al₂O₃ phase transformation to a higher temperature, lowered the crystallite growth rate, and prevented the occurrence of intragranular ZrO₂ particles during sintering.

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        Preparation and characterization of superhydrophobic coatings

        Hsing-I Hsiang,Ming-Tsai Liang,Yu-Lun Chang,Hung-Chin Huang,Fu-Su Yen 한양대학교 세라믹연구소 2010 Journal of Ceramic Processing Research Vol.11 No.3

        To obtain a surface with water-repelling and self-cleaning abilities attracts much interest in the nanotechnology age. In this study, a perfluroalkyl surfactant (perflurodecanoic acid, PFDA) was coated on nano-sized boehmite surfaces to obtain hydrophobic nano-particles via surface modification. Then the hydrophobic boehmite was coated on a transparent plastic film using spin-coating to obtain a hydrophobic film. The effects of various amounts of hydrophobic polymer on the adsorption behavior and contact angle for hydrophobic properties were investigated using FTIR, and a contact-angle meter. The adsorption of PFDA onto the surface of boehmite takes place through ionic bonding. The contact angles of the thin film prepared by spin coating PFDA-modified-boehmite on glass substrates were above 150o as the adsorption of PFDA onto the surface of boehmite reached saturation.

      • Clinical Significance of Smudge Cells in Peripheral Blood Smears in Hematological Malignancies and Other Diseases

        Chang, Chih-Chun,Sun, Jen-Tang,Liou, Tse-Hsuan,Kuo, Chin-Fu,Bei, Chia-Hao,Lin, Sheng-Jun,Tsai, Wei-Ting,Tan, N-Chi,Liou, Ching-Biau,Su, Ming-Jang,Yen, Tzung-Hai,Chu, Fang-Yeh Asian Pacific Journal of Cancer Prevention 2016 Asian Pacific journal of cancer prevention Vol.17 No.4

        Background: It is reported that the percentage of smudge cells in the blood smear could be a prognostic indicator in chronic lymphocytic leukemia. However, the clinical significance of smudge cells in other hematological malignancies, solid tumors or non-malignant diseases is less clear. Hence, this study was conducted to survey the clinical significance of smudge cells in hematological cancers and other disorders. Materials and Methods: From January to November, 2015, the clinical data of patients who received blood examination with differential counts for clinical purpose and were found to have smudge cells in the peripheral blood film in Far Eastern Memorial Hospital were selected. The percentage of smudge cells and patient outcomes were evaluated for further univariate and survival analyses. Results: A total of 102 patients with smudge cells in their blood smears were included. Smudge cells were frequently presented in out-of-hospital cardiac arrest (OHCA; n=30), infections (n=23), hematological cancers (n=23) and solid cancers (n=10). There was no relationship between the percentage of smudge cells and the patient mortality in all diseases (OR: 1.08, 95% CI: 0.47-2.48, P=1.000) as well as the OHCA group (OR: 1.91, 95% CI: 0.38-9.60, P=0.694). It was observed that in patients with all cancers with the percentage of smudge cells less than 50% had a lower mortality rate in comparison with those who had the percentage of smudge cells of 50% or more (OR: 22.29, 95% CI: 2.38-208.80, P<0.001). Additionally, it was seemingly that patients with smudge cells of 50% or more had a lower survival rate than those with smudge cells less than 50% in all cancers with follow-up at 2-month intervals, but without statistical significance (P=0.064). Conclusions: Our survey indicated that in all cancers, those who had higher percentage of smudge cells were prone to have poor outcomes when compared with the subjects with lower percentage of smudge cells. This finding was quite different from the results of previous studies in which the race-ethnicity of most study populations was non-Asian; hence, further investigations are required. Besides, there was no apparent association of the percentage of smudge cells with patient outcomes in all diseases, including OHCA.

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