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      • KCI등재

        Improved photoluminescence and monodisperse performance of colloidal CdTe quantum dots with Cannula method

        Erdem Elibol,Pınar Sevim Elibol,Musa Çadırcı,Nedim Tutkun 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.4

        Colloidal quantum dots are nano semiconductor materials that have been found in many applications, producing multiple exciton generation, unique optical and electronic properties, adjustable in size and bandwidth. Synthesized QDs are expected to exhibit high photoluminescence quantum yield and monodisperse properties according to their application area. Cannula method was adapted together with the organometallic synthesis method for the first time in the literature to increase the photoluminescence quantum yield of organometallic CdTe QD and minimize the full width at half maximum value of the photoluminescence band. Injection of precursors by the Cannula method is much faster than the injecting with the conventional method of using a glass syringe, which limits the size distribution in the solution during synthesis. In addition, the fastest injection method using Cannula method yields the shortest full width half maximum value of 27.20 nm for CdTe QDs in the literature. The photoluminescence quantum yield value of the CdTe QDs synthesized by the classical method was 8.12±2.1%, while the photoluminescence quantum yield of the CdTe QDs synthesized by the Cannula method was increased to 25.66±2.1%.

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        Radiological noninvasive assessment of ureteral stone impaction into the ureteric wall: A critical evaluation with objective radiological parameters

        Ozlem Elibol,Kadihan Yalcin Safak,Ayse Buz,Bilal Eryildirim,Kutluhan Erdem,Kemal Sarica 대한비뇨의학회 2017 Investigative and Clinical Urology Vol.58 No.5

        Purpose: To determine the predictive value of certain radiological parameters for an objective asssessment of the presence of ureteral stone impaction. Materials and Methods: Seventy-nine patients with a single proximal ureteral stones were retrieved from the departmental database. Both clinical and particularly radiological data of all cases were well evaluated on this aspect. In addition to the time period between the first colic attack and definitive management; diameter of proximal ureter and renal pelvis, longitudinal and transverse stone size, Hounsfied unit (HU) of the stone and lastly ureteral wall thickness at the impacted stone site were all carefully evaluated and noted. Results: Patients had a single proximal ureteral stone. While mean age of the cases was ranged 20 to 78 years; mean stone size was 15.62±4.26 mm. Evaluation of our data demonstrated that although there was a statistically significant correlation between ureteral wall thickness and patients age, transverse diameter of the stone, ureteral diameter just proximal to the stone, renal pelvic diameter and the duration of renal colic attacks; no correlation could be demonstrated between patients sex and the HU of the stone. Conclusions: Prediction of the presence and degree of proximal ureteral stone impaction is a challenging issue and our data indicated a highly significant correlation between ureteral wall thickness and the some certain radiological as well as clinical parameters evaluated which will give an objective information about the presence of impaction which may in turn be helpful in the follow-up and also management plans of such calculi.

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