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SYNTHESIS AND CHEMISTRY OF TRIS (β,γ-OXIMINOALKYL)AMINES PART I. HOMOTRISOXIMES
Yeong In JUNG,Elena Shalamova,Artem N. Semakin,Jin Ho OH 국제과학영재학회 2013 APEC Youth Scientist Journal Vol.5 No.-
Tris(β–oximinoalkyl)amines are well known as ligands and precursors for 1,4,6,10- tetraadamantanes. With the increasing attention to tris(β–oximinoalkyl)amines, researches of homoanalogues of these compounds have been started. Ways to introduce γ-oximinoalkyl substitutes to design mixed β- and γ- trisoximes have been developed. However, only synthesis of homotrisoximes with two same substitutes, having symmetrical structure, has been done. In this research, we tried to synthesize homotrisoximes with three different substitutes by adding radicals.