Preparation of mixed matrix PES-based nanofiltration membrane filled with PANI-co-MWCNT composite nanoparticles

Abdolreza Moghadassi,Ehsan Bagheripour,Sayed Mohsen Hosseini 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.4

Mixed matrix polyethersulfone/PANI-co-MWCNTs composite nanoparticle nanofiltration membrane was prepared by casting solution technique. Polyvinylpyrrolidone was also used as membrane pore former in membrane fabrication. The effect of polyaniline-co-multi walled carbon nanotubes composite nanoparticle concentration in the casting solution on membrane structure and performance was investigated. Scanning optical microscopy and scanning electron microscopy, FTIR analysis, porosity, mean pore size, contact angle, water content, NaCl/Na2SO4 rejection, water flux, tensile strength measurements and 3D surface image were also carried out in membrane characterization. SOM images showed nanoparticle agglomeration at high additive loading ratio. SEM images showed the membrane sub-layer porosity and thickness were changed by use of nanoparticles in membrane matrix. The membrane water content, porosity and pore size were increased by increase of nanoparticle concentration, except for 1%wt. Use of PANI-co- MWCNT nanoparticles in the membrane matrix caused a decrease of membrane contact angle from 63.43 to 46.76o. Salt rejection and water flux were improved initially by increase of nanoparticle concentration up to 0.1%wt and then decreased by more additive concentration. In addition, the membranes tensile strength was reduced by increase of PANI-co-MWCNTs composite nanoparticle concentration. 3D surface images showed a smoother surface for mixed matrix membrane filled with 0.1wt% PANI-co-MWCNTs. Modified membrane containing 0.1wt% composite nanoparticles showed better performance compared to others.

Adapting the performance and physico-chemical properties of PES nanofiltration membrane by using of magnesium oxide nanoparticles

Sayed Mohsen Hosseini,Ehsan Bagheripour,Mohsen Ansari 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.6

A new mixed matrix Polyethersulfone (PES)-co-Magnesium oxide nanoparticles (MGO) nanocomposite nanofiltration membrane was prepared through phase inversion method by using polyvinylpyrrolidone (PVP) as pore former and N, N dimethylacetamide (DMAc) as solvent. The influence of MGO nanoparticles concentration in the membrane matrix on the separation performance and physico-chemical characteristics of prepared membrane was studied by scanning electron microscopy, surface analysis, porosity measurement, water contact angle, permeability flux, salt rejection, antifouling property, and tensile strength. SEM images exhibited situating of MGO nanoparticles on the top surface of mixed matrix prepared membranes. SEM analysis also showed formation of a dense nanoparticle layer on the surface of prepared membrane at high additive concentration. Surface analysis results that revealed membrane surface roughness was increased initially by addition of MGO and then was decreased. Measured porosity showed reduction behavior for all prepared membranes filled with MGO nanoparticles. The membrane surface hydrophilicity was enhanced 35% by incorporating MGO nanoparticles into the membrane matrix. Results showed that membrane permeation flux was improved 32% by utilizing of MgO nanoparticles into the membrane matrix. Salt rejection was also improved 49% by using MGO nanoparticles in the membrane matrix relatively. The modified membranes filled with different concentrations of MGO nanoparticles showed higher antifouling properties and tensile strength compared to the neat PES membrane.

Fabrication of novel polyethersulfone based nanofiltration membrane by embedding polyaniline-co-graphene oxide nanoplates

Mojtaba Moochani,Abdolreza Moghadassi,Sayed Mohsen Hosseini,Ehsan Bagheripour,Fahime Parvizian 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.9

Mixed matrix polyethersulfone (PES) based nanofiltration membrane was prepared through phase inversion method by using of polyvinylpyrrolidone (PVP) as pore former and N, N dimethylacetamide (DMAc) as solvent. Polyaniline-co-graphene oxide nanoplates (PANI/GO) were utilized as additive in membrane fabrication. The PANI/ GO nanoplates were prepared by polymerization of aniline in the presence of graphene oxide nanoplates. FTIR analysis, scanning electron microscopy (SEM), scanning optical microscopy (SOM), 3D images surface analysis, water contact angle, water content tests, tensile strength tests, porosity tests, salt rejection and flux tests were used in membrane characterization. FT-IR results verified formation of PANI on graphene oxide nanoplates. SOM images showed uniform particles distribution for the mixed matrix membranes. SEM images also showed formation of wide pores for the modified membranes. Water flux showed constant trend nearly by use of PANI/GO in the casting solution. Opposite trend was found for the membrane surface hydrophilicity. Salt rejection was enhanced sharply by utilizing of PANI/ GO. The membrane’s tensile strength was improved by increase of PANI/GO concentration. The water content was increased initially by use of PANI/GO nanoplates up to 0.05%wt into the casting solution and then decreased. Membrane porosity was also enhanced by using of PANI/GO nanoplates. Modified membrane containing 0.5%wt PANI/ GO nanoplates showed more appropriate antifouling characteristic compared to others.

Surface modification of cation exchange membranes by graft polymerization of PAA-co-PANI/MWCNTs nanoparticles

Sayed Mohsen Hosseini,Mahsa Nemati,Ehsan Bagheripour,Sayed Siavash Madaeni 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.3

Surface modification of polyvinylchloride based heterogeneous cation exchange membrane was performed by graft polymerization of PAA and PAA-co-PANI/MWCNTs nanoparticles. The ion exchange membranes were prepared by solution casting technique. Spectra analysis confirmed graft polymerization clearly. SEM images illustrated that graft polymerization covers the membranes by simple gel network entanglement. The membrane water content was decreased by graft polymerization of PAA-co-PANI/MWCNTs nanoparticles on membrane surface. Membrane transport number and selectivity declined initially by PAA graft polymerization and then began to increase by utilizing of composite nanoparticles in modifier solution. The sodium and barium flux was improved sharply by PAA and PAAco- 0.01%wt PANI/MWCNTs graft polymerization on membrane surface and then decreased again by more increase of PANI/MWCNTs nanoparticles content ratio in modifier solution. The electrodialysis experiment results in laboratory scale showed higher dialytic rate in heavy metals removal for grafted-PAA and grafted-PAA-co-PANI/MWCNTs modified membrane compared to pristine one. Membrane areal electrical resistance was also decreased by introducing graft polymerization of PAA and PAA-co-PANI/MWCNTs NPs on membrane surface.

Tailoring the separation performance and antifouling property of polyethersulfone based NF membrane by incorporating hydrophilic CuO nanoparticles

Sayed Mohsen Hosseini,Fatemeh Karami,Samaneh Koudzari Farahani,Samaneh Bandehali,Jiangnan Shen,Ehsan Bagheripour,Amin Seidypoor 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.5

CuO/PES composite membranes were fabricated through phase inversion method, focusing on fouling reduction and improving separation performance. Copper oxide nanoparticles were used as filler additive in the membrane structure. The effect of the embedded CuO nanoparticles on the morphology was studied by considering SEM, SOM and 3D surface images. Flux recovery ratio (FRR%), water contact angle, water content, mechanical tensile strength, porosity and mean pore size, salt rejection and water flux were investigated to evaluate the performance of fabricated membranes. The SOM images showed a uniform surface for the modified membranes. SEM images showed a finger-like structure for the modified membranes. Results also denoted an increment in porosity and mean pore size of membrane at low concentration of CuO NPs, whereas the opposite trend was found at higher concentration of nanoparticles. Utilizing CuO NPs enhanced the membrane tensile strength obviously. PWF significantly was improved by applying CuO NPs in membrane matrix. Highest PWF (42.63 L/m2h) was observed for PES-0.05 wt% CuO blended membrane, whereas it was 10.41 (L/ m2h) for pristine ones. Salt rejection also measured 82% for virgin membrane and 63-90% for modified membranes. Moreover, FRR% were measured (~77% to ~93%), while the pristine membrane showed ~63% FRR%.