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Yang Zhang,Zeyang Wang,Ting Liu,Bo Yang,Shu Hu,Heng Li,ChuanXiang Sheng 대한금속·재료학회 2022 ELECTRONIC MATERIALS LETTERS Vol.18 No.3
On hot substrates with a temperature of 100 °C, the qualities of two-dimensional perovskite PEA2MA2Pb3I10(PEA = phenethylammonium,MA = methylammonium) films have been explored which are constructed with different spin-casting speeds. These films are performed at the speed of 1000, 2000, 4000, and 6000 revolution per minute (RPM). Below 4000 r, a higherRPM results in higher crystalline quality with more uniform morphology. Correspondingly, 4000 r devices show better performanceon average (4.3% power conversion efficiency) and less hysteresis in the J-V curve than 1000 r (3.6%) and 2000 rdevices (3.4%). However, for devices that were fabricated at 6000 r, inferior performance (2.8% on average) may not bepredicted simply by the morphology characterization or optical measurement results at room temperature; instead, carriertrapping states can occur that result in thermally activated PL below 200 K with an activation energy of 18 meV, which donot occur in the 1000 r, 2000 r, and 4000 r films. Our results suggest that for evaluating 2D perovskite films prior to fabricatingoptimal devices, multiple morphology characterizations and optical measurements, including of low-temperature PL,will be helpful.