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        Studies on the characterization of sulfur and coloration in borosilicate glasses

        Taro Asahi,Susumu Nakayama,Tokuro Nanba,Hajime Kiyono,Hiroshi Yamashita,Takashi Maekawa 한양대학교 세라믹연구소 2008 Journal of Ceramic Processing Research Vol.9 No.4

        Ternary alkali borosilicate glasses containing sulfur were prepared by a conventional melt quenching method, and their chemical bonding states were investigated based on XPS and 29Si,11B MAS-NMR measurement. The glass samples changed in color from blue to reddish brown due to the state of the sulfur and their glass compositions. From S2p photoelectron spectra, it can be seen that the sulfur exists with a negative charge in the glass. The forming of non-bridging oxygen components was observed from O1s photoelectron spectra of the glasses, which colored to brown and reddish brown. Furthermore, a signal from silicon atoms coordinated to the sulfur was detected in these glasses by the 29Si MAS-NMR measurement. From these results, it is considered that sulfur atoms bonded silicon atoms at the forming range of the non-bridging oxygen component. Ternary alkali borosilicate glasses containing sulfur were prepared by a conventional melt quenching method, and their chemical bonding states were investigated based on XPS and 29Si,11B MAS-NMR measurement. The glass samples changed in color from blue to reddish brown due to the state of the sulfur and their glass compositions. From S2p photoelectron spectra, it can be seen that the sulfur exists with a negative charge in the glass. The forming of non-bridging oxygen components was observed from O1s photoelectron spectra of the glasses, which colored to brown and reddish brown. Furthermore, a signal from silicon atoms coordinated to the sulfur was detected in these glasses by the 29Si MAS-NMR measurement. From these results, it is considered that sulfur atoms bonded silicon atoms at the forming range of the non-bridging oxygen component.

      • Complete Analysis of Steady-State and Efficiency Considerations in a Forward-Flyback Mixed Converter

        Yoshito Kusuhara,Tamotsu Ninomiya,Asahi Nakayama,Shin Nakagawa 전력전자학회 2007 ICPE(ISPE)논문집 Vol.- No.-

        This paper presents a novel DC-DC converter where both forward and Flyback actions are mixed. Previously, we proposed this converter that has prominent features of reducing the voltage of main switch and the current ripple of output inductor, and as a result, the high efficiency and the size reduction were obtained as reported in the previous paper. And, this paper presents that this converter has four operation modes when the turns ratio of the second and the third windings of the transformer is set to be a certain value. Furthermore, these operation modes are analyzed through the extended state-space averaging method, and are confirmed by simulation. These characteristics are shown by means of a three-dimensional graphics method. This paper presents the detailed analyses of static characteristics for the four operation mode used three-dimensional expression of load characteristics with another winding turns ratio by the extended state-space averaging method.

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