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Lee, Sungsik,Nathan, Arokia,Alexander-Webber, Jack,Braeuninger-Weimer, Philipp,Sagade, Abhay A.,Lu, Haichang,Hasko, David,Robertson, John,Hofmann, Stephan American Chemical Society 2018 ACS APPLIED MATERIALS & INTERFACES Vol.10 No.13
<P>A positive shift in the Dirac point in graphene field-effect transistors was observed with Hall-effect measurements coupled with Kelvin-probe measurements at room temperature. This shift can be explained by the asymmetrical behavior of the contact resistance by virtue of the electron injection barrier at the source contact. As an outcome, an intrinsic resistance is given to allow a retrieval of an intrinsic carrier mobility found to be decreased with increasing gate bias, suggesting the dominance of short-range scattering in a single-layer graphene field-effect transistor. These results analytically correlate the field-effect parameters with intrinsic graphene properties.</P> [FIG OMISSION]</BR>
Surface-Effect-Induced Optical Bandgap Shrinkage in GaN Nanotubes
Park, Young S.,Lee, Geunsik,Holmes, Mark J.,Chan, Christopher C. S.,Reid, Benjamin P. L.,Alexander-Webber, Jack A.,Nicholas, Robin J.,Taylor, Robert A.,Kim, Kwang S.,Han, Sang W.,Yang, Woochul,Jo, Y. American Chemical Society 2015 NANO LETTERS Vol.15 No.7
<P>We investigate nontrivial surface effects on the optical properties of self-assembled crystalline GaN nanotubes grown on Si substrates. The excitonic emission is observed to redshift by ∼100 meV with respect to that of bulk GaN. We find that the conduction band edge is mainly dominated by surface atoms, and that a larger number of surface atoms for the tube is likely to increase the bandwidth, thus reducing the optical bandgap. The experimental findings can have important impacts in the understanding of the role of surfaces in nanostructured semiconductors with an enhanced surface/volume ratio.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/nalefd/2015/nalefd.2015.15.issue-7/acs.nanolett.5b00924/production/images/medium/nl-2015-00924p_0006.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/nl5b00924'>ACS Electronic Supporting Info</A></P>