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Thermodynamic Assessment of the Pbo-Zro_2 System
Koo, Bon-Keup,Liang, Pian,Seifert, Hans Ju¨rgen,Aldinger, Fritz 대전산업대학교 반도체기술연구소 1999 半導體技術硏究所報 Vol.1 No.-
The thermodynamic properties and phase diagram of the PbO-Zro_2 system have been critically assessed using the Thermo-Cale program. Excess Gibbs energies were expressed by Redlich-Kister polynomials for the solid phases, by the two-sublattice ionic liquid model for the liquid phase and by the compound energy model for the solid solution phase. All solid phases were treated as stoichiometric compounds.