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      • SCOPUSKCI등재

        Study on Microstructure and Corrosion Characteristics of Zr-0.8Sn-xNb Ternary Alloys

        김현길,정용환,위명용,Kim, Hyeon-Gil,Jeong, Yong-Hwan,Wi, Myeong-Yong Materials Research Society of Korea 1999 한국재료학회지 Vol.9 No.5

        고연소도 핵연료피복관용 신합금 재료를 개발하기 위한 연구로 Zr-0.8Sn-xNb(x = 0.2,0.4,0.8, 1.0) 계 합금을 제조하여 Nb 첨가량이 Zr 합금의 미세구조 및 부식특성에 미치는 영향을 조사하였다. 미세조직 관찰결과 Nb첨가량이 증가함에 따라 결정립의 크기는 강소하였고 석출물의 량은 증가하였다. $360^{\circ}C$ 물 분위기에서 부식시험 한 결과 Nb 함량이 적을수록 부식저항성이 증가하는 경향을 나타냈으며며, Zr-0.8Sn-0.2Nb 합금이 가장 우수한 부식저항성을 보였다. 동얼 두께의 산화막에 대하여 XRD 분석한 결과, 내식성이 우수한 0.2 wt.% Nb 합금에서는 산화막내 tetra-$ZrO_2$의 분율이 높게 관찰되었다. 합금설계 관점에서 Zr-O.8Sn-xNb 합금계에 Nb올 첨가할때 Nb은 고용도 이하로 첨가되어야 한다고 사료된다. To develop advanced cladding materials, the effect of Nb addition on the microstructure and corrosion characteristics of Zr-0.8Sn-xNb alloys was investigated. As the Nb content increased, the grain size decreased and the volume fraction of precipitates increased. It was observed from the corrosion test at $360^{\circ}C$ that the corrosion resistance increased with decreasing Nb content. The best corrosion resistance was obtained in Zr-0.8Sn-0.2Nb alloy with high volume fraction of tetra-$ZrO_2$in the oxide. Therefore, it is suggested that Nb in theZr-0.85Sn-xNb system should be added within the solubility limit of Nb from the viewpoint of alloy design.

      • Zircaloy-4와 Zr-2.5Nb 합금의 부식과 미세조직에 미치는 냉각속도와 소둔온도의 영향

        정용환,정연호,김현길,위명용,Jeong, Yong-Hwan,Jeong, Yeon-Ho,Kim, Hyeon-Gil,Wee, Myung-Yong 한국재료학회 1998 한국재료학회지 Vol.8 No.11

        To investigate the effect of cooling rate and annealing temperature on the corrosion of Zircaloy-4 and Zr-2. 5Nb alloys, autoclave corrosion tests were performed at $500^{\circ}C$ for the specimens prepared by various heat treatments. The specimens were heat-treated at $1050^{\circ}C$ for 30 minutes and cooled by ice-brine quenching, water quenching, oil quenching, air cooling, and furnace cooling. To investigate the effect of annealing temperature, the specimens were annealed at $\alpha$, ($\alpha$+$\beta$)-, and $\beta$-temperatures. It was observed from the $500^{\circ}C$ corrosion test that nodular corrosion occurred on the Zircaloy-4 alloy but did not occur on the Zr-2.5Nb alloy. The corrosion resistance of Zircaloy-4 increased with increasing the cooling rate. On the other hand, the corrosion resistance of Zr-2.5Nb decreased with increasing the cooling rate and the annealing temperature. It is suggested that corrosion resistance of Zircaloy-4 would be controlled by the distribution of Fe and Cr element in the matrix and precipitates, while that of Zr-2.5Nb alloy the niobium concentration and $\beta_{-Nb}$ phase. Zircaloy-4와 Zr-2.5Nb 합금의 부식에 미치는 냉각속도와 소둔온도의영향을 조사하기 위해서 여러 가지 방법으로 열처리된 시편에 대해서 autoclave 부식시험을 실시하였다. 냉각속도의 영향을 조사하기 위해서 시편을 $1050^{\circ}C$에서 30분 가열 후 염빙수냉, 수냉, 유냉, 공냉, 노냉의 방법에 의해 열처리하였으며, 소둔온도의 영향을 조사하기 위해서 $\alpha$온도, $\alpha$+$\beta$온도, $\beta$온도구역에서 열처리하였다. $500^{\circ}C$부식시험 결과, Zircaloy-4합금에서는 nodule형 부식이 발생되는 반면에 Zr-2.5Nb 합금에서는 nodule형 부식이 발생되지 않았다. Zirfcaloy-4 합금에서는 nodule형 부식이 발생되는 반면에 Zr-2.5Nb 합금에서는 nodule형 부식이 발생되지 않았다. Zircaloy-4합금은 냉각속도가 빠를수록 내식성이 증가하는 반면에 Zr-2.5Nb합금은 냉각속도가 빠를수록 내식성이 감소하는 경향을 보였다. 또한 소둔온도가 증가할수록 Zr-2.5Nb 합금의 내식성은 감소하는 결과를 보였다. Zircaloy-4의 내식성은 Fe, Cr 원소의 기지내 분포와 석출물의 분포에 의해 지배를 받으며 Zr-2.5Nb 합금의 내식성은 기지조직내의 Nb 농도와 $\beta_{-Nb}$상에 의해 지배를 받는 것으로 사료된다.

      • KCI등재

        Nb 및 Cr 첨가에 따른 지르코늄 합금의 부식거동

        김윤호,목용균,김현길,이종현,Kim, Yoon-Ho,Mok, Yong-Kyoon,Kim, Hyun-Gil,Lee, Jong-Hyeon 한국재료학회 2015 한국재료학회지 Vol.25 No.8

        The effects of Nb and Cr addition on the microstructure, corrosion and oxide characteristics of Zr based alloys were investigated. The corrosion tests were performed in a pressurized water reactor simulated-loop system at $360^{\circ}C$. The microstructures were examined using OM and TEM, and the oxide properties were characterized by low-angle X-ray diffraction and TEM. The corrosion test results up to 360 days revealed that the corrosion rates were considerably affected by Cr content but not Nb content. The corrosion resistance of the Zr-xNb-0.1Sn-yCr quaternary alloys was improved by an increasing Nb/Cr ratio. The crystal structure of the precipitates was affected by a variation of the Nb/Cr ratio. The Zr-Nb beta-enriched precipitates were mainly formed in the high Nb/Cr ratio alloy while $Zr(NbCr)_2$ precipitates were frequently observed in the low Nb/Cr ratio alloy. The studies of oxide characteristics revealed that the corrosion resistance was related to the crystal structure of the precipitate.

      • 잔류유효긴장력 추정에 의한 철도교 PSC Beam의 내하력 평가기법

        이승원(Lee Seong-Won),이기성(Lee Ki-Seong),김현길(Kim Hyeon-Gil) 한국철도학회 2005 한국철도학회 학술발표대회논문집 Vol.- No.-

        This study is the evaluation of rating of railway prestressed concrete beam bridges by prediction of residual effective prestress force. Therefore, developed prediction method is based on the center camber of prestressed concrete beam, structural design report of various PSC beams, construction reference materials of PSC beams. Both rating evaluation and residual effective prestress force by developed method is compared with evaluation by structural design. This comparison results shows that this developed method is very effective method. Therefore evaluation of rating by prediction of residual effective prestress force will be used for evaluation of the rating of railway PSC beam bridges.

      • 中原郡 嚴政面 所在 胎室에 對하여

        金顯吉 忠州大學校 1984 한국교통대학교 논문집 Vol.17 No.1

        There are two Taesils(胎室) which are found recently in Judong(酒洞) village, Eomjeong Myeon, Jung-weon Gun,(中原郡 嚴政面) and the writer verified from the examination that one of them is the prince Sungseon Gun's(崇善君) and the other is the prince Nakseon Gun's(樂善君), who were born from the second queen consort of the king Injo (仁祖). The writer also examined in this study the laying out process of Taesil of the Great King, Gyeong-Jong, (景宗大王) and tried to outline the relationship of Taesils in Choseon dynasty.

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