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아세트화 아크릴 공중합체 - 올레인산 혼합 에멀젼계 방수제 제조연구
김영근,황용현 ( Young Geun Kim,Yong Hyun Hwang ) 한국유화학회 1996 한국응용과학기술학회지 Vol.13 No.3
EMA-co-DAMA were synthesized form 2-diethylaminoethyl metacrylate and ethylhexyl metacrylate in acrylmonomer. To facilitate water emulsification, acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measure by GPC, and C.H.N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier[(PDCM-PEM) water proof agent of cement for concrete in building construction] was prepared by blending of the guaternized acrylic copolymer syndisized above, sodium silicate, sodium gluconate and oleic acid emulsion. The result with prepared polymer dispersion of cement modifier was examined, and it was found that excellent waterprooffing effect ; Water permeability ratio is 0.50 under the water pressure of 100g/cm^2 and 0.60 under 3kg/cm^2, and water absorption ratio is 0.42∼0.50 and 1.0∼1.02 compressive strength ratio at mixed of water/PDCM-PEM is 50 times.