http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
제철 슬래그를 이용한 광물 탄산화 기술의 개발 현황과 연구 방향
손민아 ( Minah Son ),김국희 ( Gookhee Kim ),한건우 ( Kunwoo Han ),이민우 ( Min Woo Lee ),임준택 ( Jun Taek Lim ) 한국화학공학회 2017 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.55 No.2
이 논문에서는 CO<sub>2</sub> 활용 기술 관점에서 광물 탄산화 기술의 하나인 제철 슬래그를 이용한 침강성 탄산칼슘(Precipitated Calcium Carbonate, PCC) 제조 기술의 개발 현황을 고찰하였다. 광물 탄산화 기술의 원리, 특징, 전세계적 개발 현향을 살펴보았고, PCC 제조기술 및 시장동향도 파악하였다. 광물 탄산화는 안정적이고 친환경적인 기술로, 산업 부산물의 경제적 처리를 가능하게 한다. 일반적으로 슬래그중 Ca 용출 및 고액 분리 과정후 상등액과 CO<sub>2</sub>의 반응을 통해 탄산칼슘을 제조한다. 이 기술은 파일럿 단계까지 기술개발이 진행되었으며(알토대학교의 Slag2PCC), 상용화를 위해서는 경제성 증대가 필요할 것으로 판단된다. 개발을 위한 핵심 기술로는 슬래그로부터 Ca의 효과적 용출 및 불순물 제거, 탄산칼슘의 입도 및 입형 제어를 통한 고부가가치화, 잔사 슬래그의 활용방안 발굴, 연속공정 구현을 위한 반응 조건 최적화 등을 들 수 있다. In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of CO<sub>2</sub> utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of CO<sub>2</sub> with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.
Natural Inhibitors for CO<sub>2</sub> Hydrate Formation
사정훈(Sa, Jeong-Hoon),이보람(Lee, Bo Ram),박다혜(Park, Da-Hye),한건우(Han, Kunwoo),전희동(Chun, Hee Dong),이건홍(Lee, Kun-Hong) 한국신재생에너지학회 2011 한국신재생에너지학회 학술대회논문집 Vol.2011 No.11
The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.