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      • KCI등재

        작업환경중 톨루엔 농도와 근로자 특성에 따른 뇨중 마뇨산 농도의 상관성

        이귀영 ( Gye Young Lee ),신택수 ( Taek Soo Shin ),홍상표 ( Sang Pyo Hong ),김광렬 ( Kwang Yul Kim ) 한국환경영향평가학회 2015 환경영향평가 Vol.24 No.2

        Correlation between occupational exposure levels to toluene and urinary hippuric acid (HA) concentrations were studied for 124 workers at 54 work places. The highest indoor toluene concentration measured at printing process was 81.116 ppm, and their geometric average concentration was as high as 12.304 ppm. The geometric average concentration of hippuric acid in urine samples from workers who are exposed to toluene was 0.714 g/g creatinine. This is almost five times higher than the average HA concentration from non-exposure workers. Printing workers showed the average HA concentration of 1.145 g/g creatinine from their urine samples. It is the highest concentration among the workers exposed to toluene. The correlation coefficient between HA concentrations in urine and indoor toluene concentration at work places was relatively high as r=0.624 (P<0.01). But the correlations of HA with sex, smoking, drinking, age and employment history was relatively low. We can express the regression equation for the urinary HA concentration which is Y = 0.037X + 0.562 as exposure toluene concentration is X. The urinary HA concentrations showed significantly increase depend on indoor toluene concentration at work place.

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        테트라하이드로퓨란 제조 및 취급 근로자의 노출특성에 관한 연구

        최호춘 ( Ho Chun Chio ),홍좌령 ( Jwa Ryung Hong ),이귀영 ( Gye Young Lee ),김두호 ( Doo Ho Kim ),박정일 ( Chung Yill Park ) 한국산업위생학회 2011 한국산업보건학회지 Vol.21 No.3

        Objectives: Tetrahydrofuran (THF) is a colorless, water-miscible organic liquid with low viscosity at standard temperature and pressure. THF has been used as a solvent and a precursor for various syntheses of polymers. However, THF is known to irritate to the eyes, skin and mucus membranes. Overexposure by inhalation, ingestion or skin contact may produce nausea, dizziness, headaches, respiratory irritation and possible skin burns. The purpose of this study is to evaluate of the worker exposure and characteristics of workers in the workplaces that use or manufacture THF. Methods: Sixteen factories in Korea, which manufacture or use THF, were selected for this study and a total of 130 air samples including 104 time-weighted average (TWA) samples and 26 short-term exposure limit (STEL) samples, were collected. Air samples were collected with charcoal tube (100mg/50mg) and analyzed by gas chromatograph/flame ionization detector(GC/FID). Results: The TWA concentration of THF was 16.05ppm (GM) at PS script printing, 2.32ppm (GM) at PVC stabilizer, 1.03ppm (GM) at Lithium triethylborohydride, 0.63ppm (GM) at Polytetramethylene ether glycol(PTMEG), 0.42ppm (GM) at Manufacturing THF, 0.13ppm (GM) at Glue and 0.12ppm (GM) at synthetic rubber/resins. Two out of sampes for PS script printing exceeded 50ppm as 8-hour exposure limit of MOEL. The short term exposure to THF was 54.77ppm (GM) at PS script printing, 17.10ppm (GM) at PTMEG, 13.76ppm (GM) at Manufacturing THF, 2.86ppm (GM) at Lithium triethylborohydride, 0.87ppm (GM) at synthetic rubber/resins and 0.13ppm (GM) Glue. We found that the highest exposure process for both the TWA and STEL samples was PS script process. Two samples exceeded 100ppm as short term exposure limit of Ministry of Employment and Labor(MOEL). Conclusions: Characteristic of STEL concentration for THF is considerably different from TWA concentration in workplaces because workers could exposure high concentration of THF in a moment when they work irregularly schedule. So exposure controls for momentary works have to be prepared, and considered the skin absorption and inhale of THF.

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