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솔-젤법에 의해 제조된 실리콘 태양전지 전극형성용 나노 글래스
강성구(Seong Gu Kang),이창완(Chang Wan Lee),정윤장(Yoon Jang Chung),김창균(Chang-Gyoun Kim),김성탁(Seongtak Kim),김동환(Donghwan Kim),이영국(Young Kuk Lee) 한국태양광발전학회 2014 Current Photovoltaic Research Vol.2 No.4
We have investigated the seed layer formation of front side contact using the inkjet printing process. Conductive silver ink was printed on textured Si wafers with 80 nm thick SiNx anti reflection coating (ARC) layers and thickened by light induced plating (LIP). The inkjet printable sliver inks were specifically formulated for inkjet printing on these substrates. Also, a novel method to prepare nano-sized glass frits by the sol-gel process with particle sizes around 5 nm is presented. Furthermore, dispersion stability of the formulated ink was measured using a Turbiscan. By implementing these glass frits, it was found that a continuous and uniform seed layer with a line width of 40㎛ could be formed by a inkjet printing process. We also investigated the contact resistance between the front contact and emitter using the transfer length model (TLM). On an emitter with the sheet resistance of 60 Ω/sq, a specific contact resistance (pc) below 10 mΩ · cm² could be achieved at a peak firing temperature around 700 °C. In addition, the correlation between the contact resistance and interface microstructures were studied using scanning electron microscopy (SEM). We found that the added glass particles act as a very effective fire through agent, and Ag crystallites are formed along the interface glass layer.