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Hamit Yurtseven,Önder Ça lar 한국화학공학회 2010 Korean Journal of Chemical Engineering Vol.27 No.1
The thermal expansivity αp is related to isothermal compressibility κT at various pressures for constant temperatures of 254.6, 274 and 297.5 K close to the melting pressure in ammonia solid III. By analyzing the experimental data for κT according to a power-law formula, a linear variation of αp with the κT is established here close to the solid-liquid transition in ammonia. Anomalous behavior of thermal expansivity αp and the isothermal compressibility κT near the melting pressure is indicative of the λ-type transition in ammonia solid III.