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Bochuan Tan,Shengtao Zhang,Wenpo Li,Xiuli Zuo,Yujie Qiang,Lihui Xu,Jiangyu Hao,Shijin Chen 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.77 No.-
Phenyl disulfide (PDF), 2,20-dithiodipyridine (DDP), 5,5-dithiobis(1-phenyl-1H-tetrazole) (DPT) werestudied as inhibitors for Cu in H2SO4 via electrochemical methods, surface morphology analysis andtheoretical calculations. Electrochemical experiments show that PDF, DDP and DPT can exhibit excellentcorrosion inhibition performance. Their order of corrosion inhibition is DPT > DDP > PDF. Surfacemorphology analysis supports the electrochemical results. The X-ray photoelectron spectroscopy (XPS)results show that S Cu bonds are detected in PDF, DDP and DPT, and N Cu bonds are detected in DDPand DPT. PDF, DDP and DPT adsorption on the Cu surface obey the Langmuir isotherm model. The resultsof quantum chemical calculations show that DPT has more active reaction sites than DDP and PDF. Molecular dynamics simulation results show that the order of binding energies of the three corrosioninhibitor molecules on the copper surface is DPT > DDP > PDF.