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- 저자 : Xingwen Zheng (검색결과 2 건)
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Hao Liu,Baomin Fan,Zining Liu,Xiaoqi Zhao,Biao Yang,Xingwen Zheng,Hua Hao 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.106 No.-
Polyaniline (PANI), poly(N-methylaniline) (PNMA) and poly(N-formylanilide) (PNFA) coatings were fabricatedover mild steel via chronoamperometric strategy in oxalate electrolyte. Scanning electron microscope(SEM), attenuated total reflection infrared spectroscopy (ATR-IR) and X-ray photoelectronspectroscopy (XPS) evidenced the polymerization of monomers. Anticorrosive effects of PANI, PNMAand PNFA coatings for steel substrate were evaluated during long-term immersion in 3.5% NaCl solutionby potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and frequency modulation(EFM). Morphological variation for coated specimens before and after immersion in NaCl solutionwas also monitored by SEM and atomic force microscope (AFM). Differentiated protection capability wereobserved for three coatings following the sequence of PNFA > PNMA > PANI. Through electrochemical andinterfacial analyses, electroactivity and physical barrier were ascertained as the critical factors, especiallythe former one, in the long-term protection capacity. Electroactivity was distinguished by the elevatedapparent current density from non-destructive EFM measurements. Furthermore, electron-donationand -withdrawal effects of N-substituents played an essential role in coating electroactivity. In detail,N-substituents improved the anodic protection and physical barrier of PNMA and PNFA coatings. Particularly, formyl with electron-withdrawal effect reinforced the anodic protection and thus the superiorthe anticorrosion efficiency of PNFA for underlying steel.
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Mengqin Zhang,Lei Guo,Mengyue Zhu,Kai Wang,Renhui Zhang,Zhongyi He,Yuanhua Lin,Senlin Leng,Valentine Chikaodili Anadebe,Xingwen Zheng 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.101 No.-
In this account, pectin components were obtained from akebia trifoliate koiaz peels with the acid extractiontechnology. The chemical constituent of the akebia trifoliate koiaz peels extract (ATKPE) was analyzedand its anti-corrosion performance for mild steel in HCl medium was investigated byelectrochemical methods, surface analysis and theoretical calculations. Experimental results show thatATKPE exhibits excellent corrosion inhibition characteristic, and its inhibition efficiency can be as highas 90% when the concentration of ATKPE is 800 mg/L. Electrochemical measurements show that ATKPEis a mixed-type corrosion inhibitor consisting with Langmuir adsorption model. In addition, SEM, AFMand contact angle observations suggests that the ATKPE may attach firmly to the metal surface by forminga barrier film. XPS and ATR-FTIR results further verify the bonding interaction between the functionalgroups and steel substrate. Meanwhile, quantum chemical calculations and molecular dynamics (MD)simulations were performed to reveal the inhibition mechanism at molecular/atomic level. In brief, ourfindings demonstrate a novel environmentally benign, efficient corrosion inhibitor for steel protection inacidic media.
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