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Synthesis and thermodynamic properties of a novel pyridinium-based asymmetrical gemini ionic liquid
Xuzhao Yang,Jun Wang,Wenyuan Zou,Jinchao Wu 한국화학공학회 2015 Korean Journal of Chemical Engineering Vol.32 No.12
A novel asymmetrical gemini ionic liquid (GIL), [1-(1-pyridinium-yl-hexyl)-6-methylpiperidinium] dihexafluorophosphate ([PyC6MPi][PF6]2) combined with pyridine, 1-methylpiperidine by 1,6-dibromohexane with PF6 − as anion, was synthesized and characterized by 1H NMR and IR. The molar heat capacity of the GIL was measured via differential scanning calorimetry from 298.15 K to 448.15 K under atmospheric pressure. No phase transition or other thermal anomaly was observed in the solid-phase region (298.15 K to 358.15 K) and liquid-phase region (403.15 K to 448.15 K). The basic properties and thermodynamic functions of the GIL, such as melting point, molar enthalpy and entropy of fusion, heat capacity, enthalpy HT-H298.15 K, and entropy ST-S298.15 K, were also determined from the experimental data. Thermal decomposition kinetics of [PyC6MPi][PF6]2 were investigated by using non-isothermal thermogravimetric analysis in pure nitrogen atmosphere at various heating rates. Thermal decomposition data were, respectively, correlated with Friedman method, Ozawa-Flynn-Wall equation, and ASTM model. The activation energy (E) and pre-exponential factor (logA) values were obtained by using the above three methods.
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Jun Wang,Hao Song,Xuzhao Yang,Wenyuan Zou,Yufei Chen,Shaochan Duan 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.8
The density, viscosity, and refractive index of a pure asymmetrical dicationic ionic liquid, 1-(1-methypiperidinium- 1-yl) pentane-(1-pyridinium) bis(trifluoromethane)sulfonamide, and its binary mixtures with acetonitrile were investigated at temperatures from 293.15 K to 323.15 K over the entire range of composition at ambient pressure. From the experimental data, the excess molar volumes, dynamic viscosity deviations, and refractive index deviations were, respectively,calculated and correlated with Redlich-Kister-type polynomials. The temperature dependence of viscosity for pure ionic liquid was described by modified Vogel-Tammann-Fulcher (VTF) equation. The enthalpy and entropy of activation for viscous flow were obtained. The values of molar refraction and polarizability indicated that the dominant interactions between ionic liquids and acetonitrile were dipole-dipole molecular interactions. These thermodynamic properties were discussed in terms of nature of molecular interactions between the ionic liquid and acetonitrile.
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