http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Samuk Pimanpang,Madsakorn Towannang,Pantiwa Kumlangwan,Wasan Maiaugree,Kunthaya Ratchaphonsaenwong,Viyada Harnchana,Wirat Jarenboon,Vittaya Amornkitbamrung 대한금속·재료학회 2015 ELECTRONIC MATERIALS LETTERS Vol.11 No.4
Pt-free TiC based electrodes were hydrothermally deposited onto FTO/ glass substrates and used as dye-sensitized solar cell (DSSC) counter electrodes. A promising efficiency of 3.07% was obtained from the annealed hydrothermal TiC DSSCs based on a disulfide/thiolate electrolyte. A pronounced improvement in performance of 3.59% was achieved by compositing TiC with carbon, compared to that of a Pt DSSC, 3.84%. TEM analysis detected that the TiC particle surfaces were coated by thin carbon layer (7 nm). The SAED pattern and Raman spectrum of TiC-carbon films suggested that the carbon layer was composed of amorphous and graphite carbon. The formation of graphite on the TiC nanoparticles plays a crucial role in enhancing the film’s reduction current to 10.12 mA/cm2 and in reducing the film impedance to 237.63 Ω, resulting in a high efficiency of the TiC-carbon DSSC.
Aunping Namfon,Kumlangwan Pantiwa,Towannang Madsakorn,Chanlek Narong,Kumnorkaew Pisist,Klangtakai Pawinee,Srepusharawoot Pornjuk,Thongnum Anusit,Chompoosor Apiwat,Jarernboon Wirat,Pimanpang Samuk,Rutt 한국물리학회 2023 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.82 No.8
CH3NH3PbI3 (MAPbI3) flm was prepared by a convective method, and its X-ray difraction spectrum displays the tetragonal perovskite structure. GeI2 and GeBr2 powders dissolve poorly in a mixed dimethylformamide-dimethylsulfoxide (DMFDMSO) solvent, but the introduction of 5 wt% 5-ammonium valeric acid iodide (5-AVAI) into the mixed DMF-DMSO solvent greatly promotes GeI2 and GeBr2 solubility. XRD spectra of the (5-AVAI)MAPbI3, MAGexPb1–xI3, and MAGexPb1–xBr2xI3–2x (x=0.0625 and 0.125) flms exhibit a tetragonal perovskite structure, but the flm morphologies become rougher than that of the pristine MAPbI3 flm. Discontinuous islands are formed on MAGexPb1–xI3 and MAGexPb1–xBr2xI3–2x (x=0.125) flms. X-ray photoemission spectroscopy (XPS) analysis detected the Ge element on all Ge-doped flms. The best performance levels of the carbon-based hole transport layer-free MAGexPb1–xI3–x (x=0.0625, η=3.63%) and MAGexPb1–xBr2xI3–2x (x=0.0625, η=2.95%) perovskite solar cells are lower than that of the pristine MAPbI3–based perovskite solar cell (η=5.28%). This is likely due to the increased surface roughness, pin-holes, isolated islands, and the decreased light absorbance of the Ge-doped flms in comparison with the pristine MAPbI3 flm.
Kumlangwan Pantiwa,Suksangrat Pitphichaya,Towannang Madsakorn,Faibut Narit,Harnchana Viyada,Srepusharawoot Pornjuk,Chompoosor Apiwat,Kumnorkaew Pisist,Jarernboon Wirat,Pimanpang Samuk,Amornkitbamrung 한국물리학회 2020 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.77 No.12
CH3NH3Pb(SCN)xI3-x films were prepared using a hot-casting method with five different Pb(SCN)2/PbI2 levels (x = 0, 0.25, 0.5, 1 and 2). Substitution of SCN- in the CH3NH3PbI3 structures induces a film color transformation from black to yellow. UV vis spectra of CH3NH3Pb(SCN)xI3-x films display an increased band gap from 1.59 eV (pure CH3NH3PbI3 film) to 2.37 eV (MAPb(SCN)2I films). Experimental XRD spectra of CH3NH3Pb(SCN)xI3-x films for increasing SCN- levels show a reduced angle of the (110) plane in the same trend as for the simulated tetragonal CH3NH3Pb(SCN)xI3-x structures. The calculated bandgap of simulated tetragonal CH3NH3Pb(SCN)xI3-x structures also increases with the SCN- concentration. Maximal efficiency, 4.56%, was gained from a carbon-based hole-transport layer (HTL)-free CH3NH3PbI3 (x = 0) perovskite solar cell. This is attributed to the low bandgap of CH3NH3PbI3 (1.59 eV). Although, the efficiency of the carbon-based HTL-free CH3NH3Pb(SCN)xI3-x solar cells decreases with increasing SCN- ratio, the excellent solar cell stability was obtained from carbon-based HTL-free CH3NH3Pb(SCN)xI3-x (x = 0.25, 0.5, 1 and 2) solar cells. This should be influenced by the presence of the hydrogen bonds between H and S and/or H and N in the CH3NH3Pb(SCN)xI3-x structures. The carbon-based HTL-free CH3NH3Pb(SCN)0.5I2.5 solar cell delivers a promising efficiency of 3.07%, and its efficiency increases by 11.40% of its initial value after 30-day storage.