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Oxygen Vacancy and Magnetism of a Room Temperature Ferromagnet Co-doped TiO2
Ikuo Nakai,M. Sasano,K. Inui,T. Korekawa,H. Ishijima,H. Katoh,Y. J. Li,M. Kurisu 한국물리학회 2013 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.63 No.3
We report the local structure and the magnetic properties of a Co-doped TiO2 prepared by usingthe solid state reaction of milling with subsequent annealing. The Co-doped TiO2 shows a hysteresisbehavior in the magnetization curve at room temperature, which maintains the same rutile-typestructure as that of the starting material TiO2. The extended x-ray absorption fine structuremeasurement reveals that it contains some oxygen vacancies only around a Co atom which occupiesa Ti site. This supports the oxygen vacancy mediated ferromagnetic exchange mechanism.