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Chemical kinetics of bean straw biofuel pyrolysis using maximum volatile release method
Wei Chen,Kalyan Annamalai,Jiafeng Sun,Yuming Chen 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.8
Maximum volatile release (MVR) methods, including single point (MVR-S) and multiple (MVR-M) points, are proposed to extract the kinetics used to predict the fuel bean straw pyrolysis process. The simulation results were compared to those of the distributed activation energy model (DAEM). For the TGA (thermogravimetric analysis) experiments, fuels were heated from ambient temperature to 1,173 K at the heating rates of 10, 20, 40, 60, 80 K min−1, and the corresponding maximum volatile release points were obtained. For the MVR-S method, both the activation energy (E) and pre-exponential factor (B) increased with increasing heating rates. For the pyrolysis weight loss process, the DAEM showed best agreement with the experimental data, followed by the MVR-M, and then the MVR-S method. However, for weight loss rate prediction, MVR-S method had the best match with the experimental data, whereas the DAEM and MVR-M method generated more errors.
Threshold magnetoresistance in anistropic magnetic 2D transition metal dichalcogenides
Xu, Hongjun,Hsu, Ming-Chien,Fuh, Huei-Ru,Feng, Jiafeng,Han, Xiufeng,Zhao, Yanfeng,Zhang, Duan,Wang, Xinming,Liu, Fang,Liu, Huajun,Cho, Jiung,Choi, Miri,Chun, Byong Sun,Ó,Coileá,in, Cormac The Royal Society of Chemistry 2018 Journal of Materials Chemistry C Vol.6 No.12
<P>Recently many novel magnetoresistance (MR) phenomena have been reported from studies of two dimensional (2D) materials. Here, we report on the exotic transport behavior of VS2. A large negative and quadratic MR of −10% is observed for an in-plane magnetic field B up to 14 T. Remarkably, when the applied field deviates from the in-plane orientation there is a threshold field, Bc, and the MR shows a plateau of near zero MR. When B < Bc, only a single state exists and the transition between quantum spin states is forbidden. Our work sheds new light on the MR of magnetic 2D materials with localized states and may spur further investigations.</P>