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Koó,s, Antal A.,Vancsó,, Pé,ter,Magda, Gá,bor Z.,Osvá,th, Zoltá,n,Kerté,sz, Krisztiá,n,Dobrik, Gergely,Hwang, Chanyong,Tapasztó,, Levente,Bir&oacu Elsevier 2016 Carbon Vol.105 No.-
<P>Heterostructures of 2D materials are expected to become building blocks of next generation nanoelectronic devices. Therefore, the detailed understanding of their interfaces is of particular importance. In order to gain information on the properties of the graphene - MoS2 system, we have investigated MoS2 sheets grown by chemical vapour deposition (CVD) on highly ordered pyrolytic graphite (HOPG) as a model system with atomically clean interface. The results are compared with results reported recently for MoS2 grown on epitaxial graphene on SiC. Our STM study revealed that the crystallographic orientation of MoS2 sheets is determined by the orientation of the underlying graphite lattice. This epitaxial orientation preference is so strong that the MoS2 flakes could be moved on HOPG with the STM tip over large distances without rotation. The electronic properties of the MoS2 flakes have been investigated using tunneling spectroscopy. A significant modification of the electronic structure has been revealed at flake edges and grain boundaries. These features are expected to have an important influence on the performance of nanoelectronic devices. We have also demonstrated the ability of the STM to define MoS2 nanoribbons down to 12 nm width, which can be used as building blocks for future nanoelectronic devices. (C) 2016 Elsevier Ltd. All rights reserved.</P>
Nemestó,thy, Ná,ndor,Bakonyi, Pé,ter,Ró,zsenberszki, Tamá,s,Kumar, Gopalakrishnan,Koó,k, Lá,szló,Kelemen, Gá,bor,Kim, Sang-Hyoun,Bé,lafi-Bak Elsevier 2018 International journal of hydrogen energy Vol.43 No.41
<P><B>Abstract</B></P> <P>Lignocellulosic biofuel, in particular hydrogen gas production is governed by successful feedstock pretreatment, hydrolysis and fermentation. In these days, remarkable attention is paid to the use of ionic liquids to make the fermentable regions of lignocellulose biomass more accessible to the biocatalysts. Although these compounds have great potential for this purpose, their presence during the consecutive fermentation stage may pose a threat on process stability due to certain toxic effects. This, however, has not been specifically elaborated for dark fermentative biohydrogen generation. Hence, in this work, two common imidazolium-type ionic liquids (1-butyl-3-methylimidazolium acetate, ([bmim][Ac]) and 1-butyl-3-methylimidazolium chloride, ([bmim][Cl])) were employed in mixed culture biohydrogen fermentation to investigate the possible impacts related to their presence and concentrations. The batch assays were evaluated comparatively via the modified Gompertz-model based on the important parameters characterizing the process, namely the biohydrogen production potential, maximum biohydrogen production rate and lag-phase time.</P> <P><B>Highlights</B></P> <P> <UL> <LI> The impact of imidazolium-type ionic liquids on biohydrogen formation was tested. </LI> <LI> The batch biohydrogen production process was evaluated kinetically. </LI> <LI> Both [bmim][Ac] and [bmim][Cl] affected the biohydrogen formation performance. </LI> <LI> The anion part of ionic liquids ([Ac]<SUP>-</SUP> vs. [Cl]<SUP>-</SUP>) demonstrated notable effect. </LI> </UL> </P>
Obregó,n, Sergio,Lee, Soo W.,Coló,n, Gerardo The Royal Society of Chemistry 2014 Dalton Transactions Vol.43 No.1
<P>Er-doped BiVO<SUB>4</SUB> are synthesized by means of a surfactant free microwave assisted hydrothermal method having good photoactivities under sun-like excitation for the degradation of methylene blue. From the structural and morphological characterization, it has been stated that the presence of Er<SUP>3+</SUP> induces a slight stabilization of the tetragonal phase, probably due to its incorporation in the BiVO<SUB>4</SUB> lattice. The best photocatalytic performances were attained for the samples with Er<SUP>3+</SUP> content higher than 3 at%. The occurrence of the Er<SUP>3+</SUP> doped tetragonal BiVO<SUB>4</SUB> clearly induces higher photocatalytic activities. The existence of a luminescence process has been related with the enhanced photoactivity observed.</P> <P>Graphic Abstract</P><P>Er<SUP>3+</SUP> doped t-BiVO<SUB>4</SUB> photocatalysts have been prepared by a microwave assisted hydrothermal method having improved solar-like photocatalytic activity. A cooperative mechanism is proposed in which the photocatalyst would efficiently exploit the wide range of the visible irradiation. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c3dt51923f'> </P>
Nemestó,thy, Ná,ndor,Bakonyi, Pé,ter,Szentgyö,rgyi, Eszter,Kumar, Gopalakrishnan,Nguyen, Dinh Duc,Chang, Soon Woong,Kim, Sang-Hyoun,Bé,lafi-Bakó,, Katalin Elsevier 2018 JOURNAL OF CLEANER PRODUCTION Vol.185 No.-
<P><B>Abstract</B></P> <P>In this paper, the enrichment of methane by membrane technology was studied by employing (i) a model as well as (ii) a real biogas mixture produced on a laboratory-scale. Thereafter, the endurance of the process was tested at an existing biogas plant. The commercial gas separation module under investigation contained hollow fiber membranes with a polyimide selective layer. During the measurements, the effect of critical factors (including the permeate-to-feed pressure ratio and the splitting factor) was sought in terms of the (i) CH<SUB>4</SUB> content on the retentate-side and (ii) CH<SUB>4</SUB> recovery, which are important measures of biogas upgrading efficiency. The results indicated that a retentate with 93.8 vol% of CH<SUB>4</SUB> – almost biomethane (>95 vol% of CH<SUB>4</SUB>) quality – could be obtained using the model gas (consisting of 80 vol% of CH<SUB>4</SUB> and 20 vol% of CO<SUB>2</SUB>) along with 77.4% CH<SUB>4</SUB> recovery in the single-stage permeation system. However, in the case of the real biogas mixture, ascribed primarily to inappropriate N<SUB>2</SUB>/CH<SUB>4</SUB> separation, the peak methane concentration noted was only 80.7 vol% with a corresponding 76% CH<SUB>4</SUB> recovery. Besides, longer-term experiments revealed the adequate time-stability of membrane purification, suggesting such a process is feasible under industrial conditions for the improvement of biogas quality.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Membrane gas separation was applied for biogas enrichment. </LI> <LI> Polyimide membrane was investigated to deliver biomethane. </LI> <LI> Significant variables affecting membrane performance were evaluated. </LI> <LI> Process efficiency was dependent on gas composition (model vs. real biogas). </LI> <LI> The gas permeation was steady in longer-terms using real biogas mixture. </LI> </UL> </P>
The Delta Scuti star 38 Eri from the ground and from space
Paparó,, M,Kollá,th, Z,Shobbrook, R R,Matthews, J M,Antoci, V,Benkő,, J M,Park, N-K,Mirtorabi, M T,Luedeke, K,Kusakin, A,Bogná,r, Zs,Só,dor, Á,Garcí,a-Hern&aac Oxford University Press 2018 MONTHLY NOTICES- ROYAL ASTRONOMICAL SOCIETY Vol.477 No.4
A requiem forAdS4×CP3fermionic self-T duality
Ó,Colgá,in, E.,Pittelli, A. American Physical Society 2016 Physical Review D Vol.94 No.10
<P>Strong evidence for dual superconformal symmetry in N = 6 superconformal Chern-Simons theory has fueled expectations that the AdS/CFT dual geometry AdS(4) x CP3 is self-dual under T duality. We revisit the problem to identify commuting bosonic and fermionic isometries in a systematic fashion and show that fermionic T duality, a symmetry originally proposed by Berkovits and Maldacena, inevitably leads to a singularity in the dilaton transformation. We show that TsT deformations commute with fermionic T duality and comment on T duality in the corresponding sigma model. Our results rule out self-duality based on fermionic T duality for AdS(4) x CP3 or its TsT deformations but leave the door open for new possibilities.</P>