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Massoudi, Abdolhossain,Amini, Issa,Ramazani, Ali,Nasrabadi, Fatemeh Zeinali,Ahmadi, Yavar Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.1
The use of Smiles rearrangement in Ugi-type couplings with tropolone allows very straightforward multicomponent formation of 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives. The Ugi four-component reaction of isocyanides with tropolone (2-hydroxy-2,4,6-cycloheptatrien-1-one), primary amines and aldehydes proceeds smoothly and cleanly under mild conditions to afford 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives in fairly good yields.
Abdolhossain Massoudi,Issa Amini,Ali Ramazani,Fatemeh Zeinali Nasrabadi,Yavar Ahmadi 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.1
The use of Smiles rearrangement in Ugi-type couplings with tropolone allows very straightforward multicomponent formation of 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives. The Ugi four-component reaction of isocyanides with tropolone (2-hydroxy-2,4,6-cycloheptatrien-1-one), primary amines and aldehydes proceeds smoothly and cleanly under mild conditions to afford 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives in fairly good yields.