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        One-Step CVD Synthesis of Few-Layer SnS2/MoS2 Vertical Heterostructures

        Hongxiao Zhao,Yong Yan,Xiaohui Song,Aodi Dong,Jian Su,Huimin Jia 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.10

        Constructing van der Waals (vdW) heterostructures with various-layered two-dimensional (2D) materials is attractive to design various materials and devices. For controllable fabrication of vdW heterostructures, it is very important to make the growth process clear. In this work, SnS2/MoS2 vertical heterostructures were synthesized by the one-step chemical vapor deposition (CVD) method. The bottom MoS2 triangle layers can be partially or completely covered by SnS2 layers. The interlayer charge separation was also observed in the heterostructures by photo-luminescence (PL) spectroscopy. The growth mechanism of SnS2/MoS2 vertical heterostructures was also discussed for the first time. MoS2 triangle layers form on the substrates at first and then grow a top layer of SnS2. This study will provide an important and practical method, as a guidance to prepare high-quality vertical heterostructures.

      • SCIESCOPUSKCI등재

        Microstructure characteristics and hydrogen storage kinetic of nano MgNi‑REO alloys

        Hongxiao Tian,Xinghu Yan,Xia Li,Feng Hu,Yongzhi Li,Zengwu Zhao 한국탄소학회 2023 Carbon Letters Vol.33 No.7

        Mg81Ni19-8wt.% REO (oxides of Lanthanum and Cerium) alloys were successfully prepared using mechanical alloying method with Mg-Ni alloy and REO powder. Phase analysis, structural characterization, and microstructure imagine of the alloys were conducted using X-ray diffraction (XRD), metallurgical microscope, and transmission electron microscopy (TEM) methods. Multi-phase structures, including the primary phase of Mg2Ni and several secondary phases of Mg + Mg2Ni, MgNi-LaO, and MgNi-CeO, were found in in the as-cast Mg81Ni19- 8wt.% REO alloys. XRD and TEM results showed that Ce exhibits variable valence behavior at various stages, and the addition of REO promotes the nanocrystalline of the alloy. The hydrogen absorption capacity of ball-milled Mg81Ni19 and Mg81Ni19- 8wt.%REO alloy for 2 h at 343 K is 1.34 wt.% and 1.83 wt.%, which are much larger than 0.94 wt.% of as-cast Mg81Ni19 alloy. The addition of REO led to a decrease of the thermal decomposition temperature of the alloy hydride by approximately 20 K and a reduction of the activation energy of the hydrogen desorption reaction by 10% and 13%, respectively.

      • KCI등재

        Synthesis and Photocatalytic Properties of SnSe2/Se Heterojunction Films

        Jing Li,Hongxiao Zhao,Yan Lei,Qingyuan Yang,Zhi Zheng 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.4

        SnSe2/Se heterojunction films were successfully grown on fluorine-doped tin oxide (FTO) glass for the first time via a one-step solvothermal route using magnetron sputtered Sn metallic precursors, Se powders as selenium source, cyclohexanol as solvent and cyclohexanol as auxiliary solvent, respectively. The SnSe2/Se heterojunction films consisted of Se nanoparticles or nanorods cluster and SnSe2 network surface layers. The crystalline phase and morphology of SnSe2/Se films were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), respectively. The photocatalysis measurements of the products for rhodamine Blue (RhB) demonstrated that SnSe2/Se heterojunction films revealed better dye degradation properties than SnSe2 nanosheet films due to the higher separation rates of photogenerated electron–hole pairs of SnSe2/Se heterojunction films, which can be confirmed by surface transient photovoltage (TPV) analyzer.

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