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RISS 인기검색어
- 검색키워드
- 저자 : Heming Luo (검색결과 5 건)
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Supercapacitive behavior of mesoporous carbon CMK-3 in calcium nitrate aqueous electrolyte
Heming Luo,Deyi Zhang,Liwen Zheng,Longyan Lei,Jingxiang Wu,Jian Yang 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.4
Calcium nitrate Ca(NO3)2 aqueous solution was found to be an effective aqueous electrolyte for a supercapacitorusing ordered mesoporous carbon as the electrode materials. The supercapacitive behavior of ordered mesoporouscarbon CMK-3 electrode in Ca(NO3)2 aqueous electrolyte was investigated utilizing cyclic voltammetry (CV),electrochemical impedance spectroscopy (EIS), and galvanostatic charge/discharge measurements. CMK-3 electrodeshows excellent supercapacitive behavior with wide voltage window, high specific gravimetric capacitance and satisfactoryelectrochemical stability in Ca(NO3)2 aqueous electrolyte. The specific gravimetric capacitance of CMK-3 electrodein Ca(NO3)2 aqueous electrolyte reaches 210 F g−1 at a current density of 1 A g−1, which is higher than that in conventionalaqueous electrolytes NaNO3 and KOH solution about 40% and 54%, respectively. The high charge density of the electricdouble layer formed at the interface of the CMK-3 electrode and Ca(NO3)2 aqueous electrolyte and the pseudo-capacitiveeffect originating from the oxygen groups on the surface of CMK-3 were believed to respond for the excellent supercapacitivebehavior of CMK-3 electrode in Ca(NO3)2 aqueous electrolyte.
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Removal of methylene blue from aqueous solution by a carbon-microsilica composite adsorbent
Deyi Zhang,Ying Ma,Huixia Feng,Heming Luo,Jiao Chen,Yuan Hao 한국화학공학회 2012 Korean Journal of Chemical Engineering Vol.29 No.6
Microsilica, one kind of industrial solid waste material, was utilized firstly to prepare a carbon-microsilica composite adsorbent (CMS). The prepared adsorbent was characterized with XPS, SEM and Gas sorption experiments. The results indicated the SO3H groups, which are very effective in capturing cationic organic dye, were introduced onto the surface of CMS; the Brunauer-Emmett-Teller (BET) surface area (SBET) and total pore volume (Vtotal) of CMS reach 51m2/g and 0.045 cm3/g, respectively. Meanwhile, the possibility of the utilization of the adsorbent for removal of methylene blue (MB) from aqueous solution was investigated. The effect of pH, contact time and initial MB concentration for MB removal were studied. Equilibrium data were modeled using the Langmuir, Freundlich and Dubinin-Radushkevich equations to describe the equilibrium isotherms. It was found that data fit to the Langmuir equation better than the Freundlich equation. Maximum monolayer adsorption capacity was calculated at different temperatures (298,308, and 318 K) reach 251.81, 283.76 and 309.70 mg/g, respectively. It was observed that adsorption kinetics obeys the pseudo- first-order equation.
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Preparation and electrochemical performance of porous carbon derived from polypyrrole
Wu Lili,Chen Xinguo,Ding Chang,Wang Pitao,Luo Heming 한국탄소학회 2023 Carbon Letters Vol.33 No.2
Supercross-linked polymers are widely used as carbon precursor materials due to their abundant carbon sources and low cost. In this paper, a supercross-linked polymer was prepared by the solvothermal method. The supercross-linked polymer as a precursor and the PPyC-800-A was synthesized by activating this with KOH. The microstructure, structure, and electrochemical performances of porous carbon PPyC-800-A were studied at different of temperature and carbon alkali ratio. According to the results, the porous carbon PPyC-800-1:2 is mainly composed of a stack of spherical particles with a high surface area of 1427.03 m2 g−1, an average pore diameter of 2.32 nm, and a high specific capacitance of 217.7 F g−1 at a current density of 1.0 A g−1 in a 6 M KOH electrolyte. It’s retention rate is 97.58% after 5000 constant current charges and discharges. With a specific capacitance decay rate of 21.91 percent, an energy density of 11.96 Wh kg−1, and a power density of 500.0 W kg−1, the current density rises from 1.0 A g−1 to 10.0 A g−1, exhibiting remarkable electrochemical properties, cycling stability, and energy production performance This study contributes experimental ideas to the field of supercross-linked polymer-derived carbon materials and energy storage.
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Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs
Zhang Dongqiang,Zhang Chi,Wang Qian,Li Shuai,Zhao Xia,Luo Heming 한국탄소학회 2020 Carbon Letters Vol.30 No.3
Metal–organic frameworks (MOFs) are network-like frameworks composed of transition metals and organic ligands con�taining oxygen or nitrogen. Because of its highly controllable composition and ordered porous structure, it has broad appli�cation prospects in the feld of material synthesis. In this work, Zn4(PYDC)4(DMF)2∙3DMF (ZPD) was synthesized via a hydrothermal method. Self-doped nitrogen porous carbon ZPDC-T was then prepared by one-step carbonization. The results show that the self-doped nitrogen porous carbon ZPDC-850 has a micro/mesoporous structure with a specifc surface area of 1520 m2 g−1 and a nitrogen content of 6.47%. When a current density is 1.0 A g−1, its specifc capacitance is 265.1 F g−1 . After 5000 times of constant current charging and discharging, the capacitance retention rate was 79.2%. Thus, self-doped nitrogen porous carbon ZPDC-850 exhibits excellent electrochemical properties and good cyclic stability. Therefore, the self-doped nitrogen porous carbon derived from MOFs can be a promising electrode material for superc
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Wu Lili,Wang Pitao,Chen Xinguo,Zhang Jianqiang,Luo Heming 한국탄소학회 2022 Carbon Letters Vol.32 No.3
Hypercrosslinked polymers HCPs have been widely used as precursors to prepare porous carbon materials because of their highly ordered porous structure and large specific surface area. In this paper, we used a solvothermal method to prepare a hypercrosslinked polymer, and the HCPC-700-A was prepared using an activation method with the hypercrosslinked polymer as the precursor. The effects of different carbon–alkali ratios on the microstructure, composition and electrochemical properties of porous carbon HCP were studied. The results show that the surface of porous carbon HCPC-700-A presents a relatively regular geometric shape, and a large number of pore structures are mainly micro- and mesopores. The specific surface area is 2074.53 m2 g−1, and the average pore size is between 1.29 and 1.93 nm. Porous carbon HCPC-700-1:2 has excellent electrochemical performance in 1 M H2SO4, and the specific capacitance is up to 464.4 F g−1 at a current density of 1 A g−1. The specific capacitance decay rate is 29.72% when the current density is increased from 1 A g−1 to 8 A g−1. After 5000 cycles, the capacitance retention rate is 91.16% at a current density of 2 A g−1, showing excellent electrochemical performance, good cycle stability and perfect energy storage performance. This research provides new experimental ideas for HCPs in the electrochemical energy storage field.
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