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Shuangchen Ma,Fang Xu,Dao Qiu,Xiangyang Chen,Ruimin Wang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.109 No.-
Selenium is a harmful trace element emitted during the combustion process of coal-fired power plants. Most of the selenium is enriched in the downstream wet flue gas desulfurization system (WFGD). Thisstudy found that S2O28 is the most important factor affecting the oxidation of selenite. In the processof simulating slurry oxidation of selenite to selenate, the presence of S2O28 can increase the oxidationrate of selenate from about 50% to about 80%. At the same time, this study also considered the influenceof selenium concentration, initial pH, SO2 concentration and temperature etc. on the transformation ofselenium species. It was believed that the application of ORP to the indication of selenite oxidation statusneeds further demonstration. Energy Dispersive X-Ray Spectroscopy (EDX) and X-ray photoelectron spectroscopy(XPS) were used to confirm the migration of selenium in the desulfurization slurry to gypsum. Inaddition, DFT calculation was performed to obtain theoretical parameters for the adsorption of seleniteand selenate by gypsum. The results of this study are helpful to understand the transformation andmigration of selenium in the desulfurization system, which provide theoretical support for the realizationof selenium in-situ control.