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        Compact nanoarchitectures of lead selenide via successive ionic layer adsorption and reaction towards optoelectronic devices

        Bhat, T. S.,Vanalakar, S. A.,Devan, R. S.,Mali, S. S.,Pawar, S. A.,Ma, Y. R.,Hong, C. K.,Kim, J. H.,Patil, P. S. Springer Science + Business Media 2016 Journal of materials science Materials in electron Vol.27 No.5

        <P>Thin films of Lead Selenide (PbSe) having compact nanoarchitectures were synthesized by a facile and cost-efficient successive ionic layer adsorption and reaction (SILAR) technique. The structural, morphological, optical and compositional properties were studied using X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), UV-vis spectrophotometer, and X-ray photoelectron spectroscopy (XPS) techniques. Moreover, the effect of SILAR cycles on the morphology of PbSe thin films was investigated. XRD patterns revealed the formation of crystalline PbSe with the cubic crystal structure. FESEM images show shape evolution from nanoparticulate to merged pyramidal-like structure with variation in size from similar to 200 to 430 nm. The optical direct band gap energy of PbSe were varies from 1.32 to 1.20 eV with the increase in deposition cycles. The HRTEM and SAED results show the crystalline nature of the sample which is in good agreement with the XRD. The electrical characterizations were performed in order to obtain the ohmic behavior in the metal-semiconductor interface. The deposited thin films show a good ohmic behavior.</P>

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        Grains and Roughage Production and Its Utilization in Asian-Australasian Region - Review -

        Bhat, P.N.,Bansil, P.C. Asian Australasian Association of Animal Productio 1999 Animal Bioscience Vol.12 No.3

        Asian-Australasian region comprises of 82 countries spread over varying agro economic zones, habitats and ecosystems varying from dry hot to humid tropics and cold deserts. The literacy standards vary from very low to almost 100 percent. On the basis of economic development there are 4 countries Japan, Australia, New Zealand and Korea which are developed countries, rest are in varying states of development and growing economically very rapidly. Based on Agro ecosystems and farming practices, we have chosen four countries for indepth study in this paper namely China, Thailand, Indonesia and India. They represent 70% of the bovine and poultry population of the region. This paper makes a comparative study of the grain and roughage production and utilization at present and in 2000 A.D. by examining information on feed rates demand patterns and feed requirements in these four countries keeping in view the size and growth of bovine and poultry population and dietary pattern of the people. It has been observed, there has so far been no country level detailed study on the livestock feed requirements. Apart from conceptual discrepancies, most of the estimates given in various reports brought out by the national governments and international agencies do not have any scientific basis. Hence an inter-country comparison is virtually impossible on the basis of the available information. We have however, attempted to analyse the dietary pattern in the different countries, feedgrains requirements, availability of feed based on the information available from the various published and unpublished reports. We have given an inter-country comparison of feed rate and feed requirements which, however, needs to be tested by carrying out a micro level study in each selected country.

      • Mesoporous architecture of TiO2 microspheres via controlled template assisted route and their photoelectrochemical properties

        Bhat, T. S.,Mali, S. S.,Korade, S. D.,Shaikh, J. S.,Karanjkar, M. M.,Hong, C. K.,Kim, J. H.,Patil, P. S. Springer Science + Business Media 2017 Journal of materials science. Materials in electro Vol.28 No.1

        <P>Anatase titanium dioxide (TiO2) microspheres were successfully synthesized via a controlled chemical route using carbon spheres as sacrificial templates. The morphology has been controlled by varying the deposition time of carbonaceous (c) spheres from 4 to 16 h with the interval of 4 h, which affect the size of TiO2 spheres. The structural, morphological, optical, compositional and photoelectrochemical properties of the TiO2 thin films were studied. X-ray diffraction (XRD) pattern confirms the formation of anatase TiO2 with the tetragonal crystal structure. Field emission scanning electron microscopy analysis revealed that the synthesized anatase TiO2 microspheres has average diameter of similar to 330-510 nm. The blueshift in optical absorption is observed due to Mie scattering. The indirect optical band gap energy of TiO2 was varied over 3.05-3.16 eV, with the increase in deposition time. The HRTEM and SAED results show the polycrystalline nature of the sample which is in good agreement with the XRD. The anatase TiO2 hollow spheres with mesoporous walls and high specific surface area i.e. 41 m(2) g(-1) was obtained using this simple method. The films were photoelectrochemically active with maximum current density 531 mu A/cm(2) under 100 mW/cm(2) illuminations.</P>

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