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        A porous multifunctional and magnetic layered graphene oxide/3D mesoporous MOF nanocomposite for rapid adsorption of uranium(VI) from aqueous solutions

        Asma Amini,Mostafa Khajeh,Ali Reza Oveisi,Saba Daliran,Mansour Ghaffari-Moghaddam,Hojat Samareh Delarami 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.93 No.-

        A novel adsorbent, GO/Fe3O4/OPO3H2/PCN-222, was successfully synthesized via graphene oxide (GO)modification with magnetic particles, phosphorous-containing groups, and a mesoporous Zr-MOF, PCN-222 (PCN stands for Porous Coordination Network), respectively, to give the nominal composite. The laststep was through a solvent-assisted ligand incorporation technique. Morphological, structural, andphysicochemical properties of the hybrid material was assessed by FT-IR, PXRD, SEM/EDX, BET surfacearea, VSM, TGA/DSC, UV–vis DRS, and ICP-OES analyses. This solid was then used for dispersive solidphase extraction of uranium ions dissolved in water. Several parameters including pH of solution,extraction and desorption times, amount of adsorbent, and type and concentration of elution solventwere investigated and optimized. The maximum adsorption capacity of adsorbent was found to be416.7 mg g 1 (pH, 6.2; amount of adsorbent, 5.0 mg; extraction time, 3.0 min) beyond what wasachievable with the individual components. In addition, various coordination modes between themultifunctional adsorbent and uranyl ions were investigated by DFT calculations in details, revealingsome favorable non-covalent cation–p interaction and strong binding of free-base porphyrin, carboxyland phosphorous-containing groups to the uranium ions. Under optimized conditions, highdetermination coefficient (R2 = 0.9994) was obtained and limit of detection and relative standarddeviation were found 0.9 mg L 1 and 2.7%, respectively

      • Factors Associated with Adherence to Colorectal Cancer Screening among Moderate Risk Individuals in Iran

        Taheri-Kharameh, Zahra,Noorizadeh, Farsad,Sangy, Samira,Zamanian, Hadi,Shouri-Bidgoli, Ali Reza,Oveisi, Helaleh Asian Pacific Journal of Cancer Prevention 2015 Asian Pacific journal of cancer prevention Vol.16 No.18

        Background: Colorectal cancer is one of the most common neoplasms in Iran. Secondary prevention (colorectal cancer screening) is important and a most valuable method of early diagnosis of this cancer. The objectives of this study were to determine the factors associated with colorectal cancer screening adherence among Iranians 50 years and older using the Health Belief Model. Materials and Methods: This cross-sectional study was conducted from June 2012 to May 2013. A convenience sample of 200 individuals aged 50 and older was recruited from the population at outpatient clinics in teaching hospitals. Data gathering tools were the Champions health belief model scale (CHBMS) with coverage of socio-demographic background and CRC screening information. Multiple logistic regression was performed to identify factors associated with colorectal cancer screening adherence. Results: The mean age of participants was $62.5{\pm}10.8$ and 75.5% were women. A high percentage of the participants had not heard or read about colorectal cancer (86.5%) and CRC screening (93.5%). Perceived susceptibility to colorectal cancer had the lowest percentage of all of the subscales. Participants who perceived more susceptibility (OR =2.99; CI 95%: 1.23-5.45) and reported higher knowledge (OR =1.29; CI 95%: 1.86-3.40) and those who reported fewer barriers (OR =.37; CI 95%:.21-.89), were more likely to have carried out colorectal cancer screening. Conclusions: Our findings indicated that CRC knowledge, perceived susceptibility and barriers were significant predictors of colorectal cancer screening adherence. Strategies to increase knowledge and overcome barriers in risk individuals appear necessary. Education programs should be promoted to overcome knowledge deficiency and negative perceptions in elderly Iranians.

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