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Amin M.T.,Alazba A.A.,Shafiq M. 한국물리학회 2022 Current Applied Physics Vol.40 No.-
In the study, the layered double hydroxide (LDH) of NiZnFe and its composites with date-palm biochar (LDHDPb) and carbon nanotubes (LDH-cnt) were synthesized for adsorbing reactive black 5 (RB5) dye from aqueous solutions. In the first 5 min, rapid adsorption was followed by a gradual increase in both dye uptake and removal efficiency of up to 60 min of starting time. In the investigated pH range (3.0–8.0), the removal efficiency linearly decreased while the sorption capacity linearly increased for all three adsorbents as their doses increased to 0.3 or 0.4 g following a decreasing trend up to 0.6 g. By increasing the initial RB5 concentration from 10 to 100 mg L-1, the removal efficiency linearly decreased. A nearly perfect fitting of the pseudo-second-order kinetic model to the adsorption data was observed; however, the Elovich kinetic model showed the heterogeneous surface of adsorbents with chemisorption. At the solid–liquid interface, from a thermodynamics point of view, we obtained the nonspontaneous nature of the adsorption of RB5 dye of the studied adsorbents with an increased disorder, which supported the endothermic nature onto the studied adsorption process. Furthermore, a nearly perfect fitting of the Langmuir model was obtained to the adsorption data, thereby suggesting the monolayer adsorption of RB5 dye onto the studied adsorbents. In the Dubinin–Radushkevich model, a good agreement of the calculated adsorption capacities to the experimental values were observed and the chemical adsorption of RB5 dye on to the studied adsorbents was proposed based on E (8 – 16 kJ mol-1).
Amin M.T.,Alazba A.A.,Shafiq M. 한국물리학회 2022 Current Applied Physics Vol.40 No.-
The nanofibrous membrane of polyacrylonitrile (NMP) was successfully synthesized after NaOH and NaHCO3 treatment aiming its functionalization using electrospinning for cadmium ion (Cd2+) adsorption. Field emission scanning electron microscopy (FE-SEM) revealed that small particles attached to the surface of functionalized PAN nanofibers. Equilibrium was attained after 60 min following a rapid uptake of Cd2+ with maximum adsorption capacity and percentage removal at an optimum solution pH of 7.0. The adsorbent dose of 0.3 g and 90 mg L-1 of initial Cd2+ concentration yielded the maximum adsorption capacity. The pseudo-second-order kinetic model was the best fitted to the adsorption data, indicating that the chemisorption is the controlling mechanism of adsorption. The physisorption was proposed based on the calculated values of the mean free energy of adsorption from the D–R isotherm (E < 8 kJ mol-1). Furthermore, three-parameter isotherm models indicated the homogeneous and heterogeneous Cd2+ adsorption onto NMP adsorbent.