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중금속 오염 철도 토양의 세척에 의한 정화 타당성 연구
백기태(Kitae Baek),신민철(Min-Chul Shin),현충호(Chung-Ho Hyun),이재영(Jae-Young Lee),강해숙(Hae-Sook Kang) 한국철도학회 2007 한국철도학회 학술발표대회논문집 Vol.- No.-
The feasibility of soil washing was investigated in the laboratory to treat heavy metals-contaminated railway soil. Various organic acids including ethylene diamine tetraacetic acid (EDTA) and citric acid as well as inorganic acids such as hydrochloric acid (HCl) and phosphoric acid were tested to evaluate washing efficiency. Generally, inorganic acid showed higher removal efficiency compared to organic acids. Specially, EDTA, which are well known as most effective washing agent to remove heavy metals from soil, was not efficient to remove heavy metals in this study. Among washing agents tested in this study, HCl was most effective. The removal of Cd, Cu, and Pb was high, however, that for Zn and Ni was less than 30% with 0.5 M HCl. This difference comes from analytical methods (Korean Standard Test Method for Soil). Aqua regia was used to extract Zn and Ni, however 0.1 N HCl was used for other metals. As a result, simple washing technology is not effective, to treat railway contaminated soil with heavy metals.