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폐스팀을 이용한 가역 고체산화물 연료전지의 기술적 경제적 해석
잡반티엔,이영덕,김영상,안국영 한국수소및신에너지학회 2019 한국수소 및 신에너지학회논문집 Vol.30 No.1
Reversible solid oxide fuel cell (ReSOC) system was integrated with waste steam for electrical energy storage in distributed energy storage application. Waste steam was utilized as external heat in SOEC mode for higher hydrogen production efficiency. Three system configurations were analyzed to evaluate techno- economic performance. The first system is a simple configuration to minimize the cost of balance of plant. The second system is the more complicated configuration with heat recovery steam generator (HRSG). The third system is featured with HRSG and fuel recirculation by blower. Lumped models were used for system performance analyses. The ReSOC stack was characterized by applying area specific resistance value at fixed operating pressure and temperature. In economical assessment, the levelized costs of energy storage (LCOS) were calculated for three system configurations based on capital investment. The system lifetime was assumed 20 years with ReSOC stack replaced every 5 years, inflation rate of 2%, and capacity factor of 80%. The results showed that the exergy round-trip efficiency of system 1, 2, 3 were 47.9%, 48.8%, and 52.8% respectively. The high round-trip efficiency of third system compared to others is attributed to the remarkable reduction in steam requirement and hydrogen compression power owning to fuel recirculation. The result from economic calculation showed that the LCOS values of system 1, 2, 3 were 3.46 ¢/kWh, 3.43 ¢/kWh, and 3.14 ¢/kWh, respectively. Even though the systems 2 and 3 have expensive HRSG, they showed higher round-trip efficiencies and significant reduction in boiler and hydrogen compressor cost.
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연료 재순환 이젝터를 이용한 연료전지-폐기물 기반 가역 고체 산화물 연료전지의 최적 설계
잡반티엔,이영덕,김영상,쿠엔,안국영 한국수소및신에너지학회 2019 한국수소 및 신에너지학회논문집 Vol.30 No.4
Reversible solid oxide fuel cell (RSOFC) has become a prospective device for energy storage and hydrogen production. Many studies have been conducted around the world focusing on system efficiency improvement and realization. The system should have not only high efficiency but also a certain level of simplicity for stable operation. External waste steam utilization was proved to remarkably increase the efficiency at solid oxide electrolysis system. In this study, RSOFC system coupled with waste steam was proposed and optimized in term of simplicity and efficiency. Ejector for fuel recirculation is selected due to its simple design and high stability. Three system configurations using ejector for fuel recirculation were investigated for performance of design condition. In parametric study, the system efficiencies at different current density were analyzed. The system configurations were simulated using validated lumped model in EBSILON® program. The system components, balance of plants, were designed to work in both electrolysis and fuel cell modes, and their off-design characteristics were taken into account. The base case calculation shows that, the system with suction pump results in slightly lower efficiency but stack can be operated more stable with same inlet pressure of fuel and air electrode.
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잡반티엔,쿠엔,안국영,배용균,이선엽,김영상 한국수소및신에너지학회 2022 한국수소 및 신에너지학회논문집 Vol.33 No.6
Cracking ammonia inside solid oxide fuel cell (SOFC) stack is a compact and simple way. To prevent sharp temperature fluctuation and increase cell efficiency, the decomposition reaction should be spread on whole cell area. This leading to a question that, how does anode thickness affect the conversion rate of ammonia and the cell voltage? Since the 0D model of SOFC is useful for system level simulation, how accurate is it to use equilibrium solver for internal ammonia cracking reaction? The 1D model of ammonia fed SOFC was used to simulate the diffusion and reaction of ammonia inside the anode electrode, then the partial pressure of hydrogen and steam at triple phase boundary was used for cell voltage calculation. The result shows that, the ammonia conversion rate increases and reaches saturated value as anode thickness increase, and the saturated thickness is bigger for lower operating temperature. The similar cell voltage between 1D and 0D models can be reached with NH3 conversion rate above 90%. The 0D model and 1D model of SOFC showed similar conversion rate at temperature over 750℃.
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교류 흐름 방식을 적용한 암모니아 공급 고체산화물 연료전지의 성능 분석
쿠엔,잡반티엔,이동근,이선엽,배용균,안국영,김영상 한국수소및신에너지학회 2022 한국수소 및 신에너지학회논문집 Vol.33 No.5
The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.
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이수용,잡반티엔,무자히드 나심,김종환,이영덕 한국수소및신에너지학회 2023 한국수소 및 신에너지학회논문집 Vol.34 No.3
Hydrogen production can be classified based on the energy source, primary reactor type, and whether or not it emits carbon dioxide. Utilizing color representation proves to be an effective means of expressing these distinctive characteristics. Among the various clean hydrogen production techniques, there has been a growing interest in turquoise hydrogen production, which involves the decomposition of methane or other fossil fuels. This method offers advantages in terms of large-scale production and cost reduction through the sale of solid- carbon byproduct. In this study, an extensive literature review was conducted to select and analyze several promising candidates for turquoise hydrogen production processes. The efficiency and economics of these processes were evaluated using stream data reported in the literature sources. The findings indicate that the levelized cost of hydrogen production (LCOH) is significantly influenced by the sales of byproducts, specifically the solid-carbon and carbon monoxide byproducts.
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Parametric Study on High Power SOEC System
TUANANH BUI(뚜안앵),YOUNG SANG KIM(김영상),VAN-TIEN GIAP(잡반티엔),DONG KEUN LEE(이동근),KOOK YOUNG AHN(안국영) 한국수소및신에너지학회 2021 한국수소 및 신에너지학회논문집 Vol.32 No.6
In the near future, with the urgent requirement of environmental protection, hydrogen based energy system is essential. However, at the present time, most of the hydrogen is produced by reforming, which still produces carbon dioxide. This study proposes a high-power electrolytic hydrogen production system based on solid oxide electrolysis cell with no harmful emissions to the environment. Besides that, the parametric study and optimization are also carried to examine the effect of individual parameter and their combination on system efficiency. The result shows that the increase in steam conversion rate and hydrogen molar fraction in incoming stream reduces system efficiency because of the fuel heater power increase. Besides, the higher Faraday efficiency does not always result a higher system efficiency.
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