(Bi,La)FeO₃-PbTiO₃ 세라믹스의 자전효과

이은구,이종국,장우양,김선재,이재갑,Lee Eun Gu,Lee Jong Kook,Jang Woo Yang,Kim Sun Jae,Lee Jae Gab 한국재료학회 2005 한국재료학회지 Vol.15 No.2

Magnetoelectric (ME) effects for lanthanum modified $BiFeO_3-PbTiO_3\;(BE-_xPT)$ solid solutions have been investigated. The value of magnetoelectric polarization coefficient, up is 10 times greater than that of $Cr_2O_3$. The results also show that up is due to a linear coupling between polarization and magnetization, and that up is independent of do magnetic bias and ac magnetic field. The ME effect is believed to be significantly enhanced due to breaking of the cycloidal spin state of a long-period spiral spin structure, via randomly distributed charged imperfections.

$Pb(Zr,Ti)O_3$ 강유전체 박막 이력곡선의 변형에 관한 연구

이은구,이종국,이재갑,김선재,Lee, Eun-Gu,Lee, Jong-Guk,Lee, Jae-Gap,Kim, Seon-Jae 한국재료학회 2000 한국재료학회지 Vol.10 No.5

다양한 Zr/Ti 비율을 갖고 있는 강유전체 PZT박막을 졸-겔 법으로 증착하였고 상부 백금전극의 제조방법과 열처리온도의 변화에 따라 강유전체 특성을 측정하여 이력곡선의 변형 원인을 조사하였다. Pt/PZT/Pt 캐패시터는 상부 백금전극을 반응성 이온 식각(RIE) 하는 과정에서 생성된 dc plasma 전압에 의하여 양의 방향으로 분극되었고 도메인 계면에 포획된 전하에 의해 내부전장이 발생되었다. PZT 박막은 sputtering으로 상부전극을 증착하는 과정에서 이력곡선의 중간에 잘룩하게 되는 시효현상이 관찰되었다. 상부전극을 제작한 후 열처리는 포획된 전하흫 제거시켜 양호한 이력곡선 특성을 되찾게 하였다. Zr/Ti 비율이 감소함에 따라 내부전장이 증가하였으며 내부전장이 없어지는 열처리온도가 증가하였다. Deformation in the hysteresis loop of $Pb(Zr,Ti)O_3$ (PZT) thin films with various Zr/Ti ratios has been studied by varying the top electrode preparation method and the annealing temperature. Pt/PZT/Pt capacitors was found to be positively poled due to dc plasma potential generated during reactive ion etch (RIE) of Rt. Internal field is formed by space charges trapped at domain boundaries. Aging phenomenon such as constriction in the middle of the hysteresis loop was observed in the PZT film with top electrode deposited by sputtering. Top electrode annealing restores the hysteresis loop by removing the space charges. As Zr/Ti ratio decrease, voltage shift increases and an-nealing temperature at which internal field disappears also increases.

Lanthanum이 첨가된BiFeO₃−PbTiO₃ 세라믹스의 전자효과에 대한 연구

이은구,김선재,이재갑,Lee, Eun-Gu,Kim, Sun-Jae,Lee, Jae-Gab 한국세라믹학회 2007 한국세라믹학회지 Vol.44 No.6

Ferroelectric, magnetic, and magnetoelectric effects for lanthanum modified $BiFeO_3-PbTiO_3$ ceramics have been investigated. The data show that magnetoelectric polarization coefficient, ${\alpha}_p$ is due to a linear coupling between polarization and magnetization, and that ${\alpha}_p$ is independent of dc magnetic bias and ac magnetic field. The values of ${\alpha}_p$ and magnetic induced susceptibility for lanthanum modified $BiFeO_3-PbTiO_3$ ceramics are much larger than those of single $BiFeO_3$ crystal. We believe that the magnetoelectric effect is significantly enhanced by breaking of the cycloidal spin state of a long-period spiral spin structure due to randomly distributed charged imperfections.

분극된 <001> 방위 Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ 단결정의 유전 특성 및 상전이

이은구,이재갑,Lee, Eun-Gu,Lee, Jae-Gab 한국재료학회 2012 한국재료학회지 Vol.22 No.7

The dielectric properties and phase transformation of poled <001>-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$(PMN-x%PT) single crystals with compositions of x = 20, 30, and 35 mole% are investigated for orientations both parallel and perpendicular to the [001] poling direction. An electric-field-induced monoclinic phase was observed for the initial poled PMN-30PT and PMN-35PT samples by means of high-resolution synchrotron x-ray diffraction. The monoclinic phase appears from $-25^{\circ}C$ to $100^{\circ}C$ and from $-25^{\circ}C$ to $80^{\circ}C$ for the PMN-30PT and PMN-35PT samples, respectively. The dielectric constant (${\varepsilon}$)-temperature (T) characteristics above the Curie temperature were found to be described by the equation$(1/{\varepsilon}-1/{\varepsilon}_m)^{1/n}=(T-T_m)/C$, where ${\varepsilon}_m$ is the maximum dielectric constant and $T_m$ is the temperature giving ${\varepsilon}_m$, and n and C are constants that change with the composition. The value of n was found to be 1.82 and 1.38 for 20PT and 35PT, respectively. The results of mesh scans and the temperature-dependence of the dielectric constant demonstrate that the initial monoclinic phase changes to a single domain tetragonal phase and a to paraelectric cubic phase. In the ferroelectric tetragonal phase with a single domain state, the dielectric constant measured perpendicular to the poling direction was dramatically higher than that measured in the parallel direction. A large dielectric constant implies easier polarization rotation away from the polar axis. This enhancement is believed to be related to dielectric softening close to the morphotropic phase boundary.

Scanning Force Microscope에 의한 (001) PMN-x%PT 단결정의 도메인 구조에 대한 연구

이은구,이재갑,Lee, Eun-Gu,Lee, Jae-Gab 한국재료학회 2009 한국재료학회지 Vol.19 No.6

The domain structures of annealed (001)-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$ (PMN-x%PT) crystals for x = 10, 20, 30, 35, and 40 at% were investigated by Polarized Optical Microscopy (POM) and Scanning Force Microscopy (SFM) in the piezoresponse mode. Both Polar Nano-Domains (PND) and long strip-like domains were clearly observed. The results also showed how the domain structure changed between phases with an increasing x in the PMN-x%PT crystals and the domain hierarchy on various length scales ranging from 40 nm to 0.1 mm. Distorted pseudo-cubic phase (x < 20%) consisted of PNDs that did not self-assemble into macro-domain plates. The rhombohedral phase (x = 30%) consisted of PNDs that began to self-assemble into colonies along preferred {110} planes. The monoclinic phase (x = 35%) consisted of miniature polar domains on the nm scale, whereas, the tetragonal phase (x = 40%) consisted of {001} oriented lamella domains on the mm scale that had internal nano-scale heterogeneities, which self-assembled into macro-domain plates oriented along {001} the mm scale.

주사 힘 현미경에 의한 (001) Pb(Mg_1/3Nb_2/3)O₃-x%PbTiO₃ 단결정의 도메인 구조 및 분극 스위칭 관찰

이은구,Lee, Eun-Gu 한국세라믹학회 2010 한국세라믹학회지 Vol.47 No.4

Domain structure and polarization switching in (001)-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$ (PMN-x%PT) crystals for x=20 and 35at% have been investigated in-situ by scanning force microscope (SFM) in a piezoresponse mode under a step DC electrical voltage. In the initial annealed condition, polar nano domains (PND) and domain striations oriented along {110} were observed in x=20 and x=35, respectively. For x=20, domain switching occurs by heterogeneous nucleation, where nucleation is not confined in the vicinity of domain boundaries, but rather can occur throughout the crystal volume. However, for x=35, domain switching tends to be preferentially initiated near pre-existing twin boundaries. With increasing the applying voltage, the nuclei density increased and assembled into {110} striations, indicating a stress-accommodated domain growth process. At higher voltage, nucleation occurs heterogeneously throughout the crystal volume.

단결정 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ 의 상전이에 미치는 전장의 영향

이은구,Lee, Eun-Gu 한국재료학회 2013 한국재료학회지 Vol.23 No.6

The structural phase transformations of $0.7Pb(Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) were studied using high resolution x-ray diffraction (HRXRD) as a function of temperature and electric field. A phase transformational sequence of cubic (C)${\rightarrow}$tetragonal (T)${\rightarrow}$rhombohedral (R) phase was observed in zero-field-cooled conditions; and a $C{\rightarrow}T{\rightarrow}$monoclinic $(M_C){\rightarrow}$ monoclinic ($M_A$) phase was observed in the field-cooled conditions. The transformation of T to $M_A$ phase was realized through an intermediate $M_C$ phase. The results also represent conclusive and direct evidence of a $M_C$ to $M_A$ phase transformation in field-cooled conditions. Beginning from the zero-field-cooled condition, a $R{\rightarrow}M_A{\rightarrow}M_C{\rightarrow}T$ phase transformational sequence was found with an increasing electric field at a fixed temperature. Upon removal of the field, the $M_A$ phase was stable at room temperature. With increasing the field, the transformation temperature from T to $M_C$ and from $M_C$ to $M_A$ phase decreased, and the phase stability ranges of both T and $M_C$ phases increased. Upon removal of the field, the phase transformation from R to $M_A$ phase was irreversible, but from $M_A$ to $M_C$ was reversible, which means that $M_A$ is the dominant phase under the electric field. In the M phase region, the results confirmed that lattice parameters and tilt angles were weakly temperature dependent over the range of investigated temperatures.

(001) Pb(Mg_1/3Nb_2/3)O₃-x%PbTiO₃ 단결정의 도메인 구조 및 상전이

이은구,Lee, Eun-Gu 한국세라믹학회 2014 한국세라믹학회지 Vol.51 No.3

The domain structures, dielectric properties, and phase transformation of (001)-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$ (PMN-x%PT) crystals for x=20, 30, 35, and 40 mole% have been investigated. PMN-20%PT consists of polar nano-domains (PND) which do not self-assemble into macro-domain plates. PMN-30%PT consists of PNDs which begin to self-assemble into colonies along preferred {110} planes. PMN-35PT consists of miniature polar domains on the nm scale. PMN-40%PT consists of {001} oriented lamella domains on the mm scale that have internal nano-scale heterogeneities. The dielectric properties of poled (001) PMN-x%PT single crystals have been measured for orientations both parallel and perpendicular to the [001] poling direction. The results of the temperature dependence of the dielectric constant and mesh scans for the 30%PT sample demonstrate that the initial monoclinic phase changes to single domain tetragonal phase and to cubic phase with increasing temperature.

수치해석을 이용한 전력 BJT의 정특성 분석

이은구,윤현민,김철성,Lee, Eun-Gu,Yun, Hyun-Min,Kim, Cheol-Seong 한국전기전자학회 2002 전기전자학회논문지 Vol.6 No.2

수치해석을 이용하여 전력 BJT의 정특성을 분석하는 방법을 제안한다. 고농도의 불순물이 주입된 영역에서 반송자 농도를 정교하게 구하기 위해 Fermi-Dirac 통계를 고려하며, 베이스 영역에서 재결합 전류를 계산하기 위해 Philips Unified 이동도 모델과 SRH 및 Auger 생성-재결합 모델을 사용한다. 제안된 방법을 검증하기 위해 현재 산업체에서 사용중인 전력 BJT의 베이스 전류를 $1.0[{\mu}A]$에서부터 $3.5[{\mu}A]$까지 $0.5[{\mu}A]$ 단위로 증가시키면서 컬렉터 전류의 실측치와 BANDIS와 비교한 결과 8.9%이내의 상대오차를 보였다. An algorithm for analyzing the characteristics of the power BJT using numerical analysis method is proposed. The Fermi-Dirac statistics is used to calculate the carrier concentration in highly doped region. Philips Unified mobility model, SRH model and Auger model is used to calculate the recombination current of base region. To verify the accuracy of the proposed method, the collector current of BANDIS is compared with the measured data in the condition of the base current increased from $1.0[{\mu}A]\;to\;3.5[{\mu}A]$. The collector current of BANDIS show a maximum relative error within 8.9% compared with the measured data.

SrTiO₃기판 위에 증착한 BiFeO₃박막의 강유전 및 자기적 특성

이은구,김선재,이재갑,Lee, Eun-Gu,Kim, Sun-Jae,Lee, Jae-Gab 한국세라믹학회 2008 한국세라믹학회지 Vol.45 No.6

$BiFeO_3$ films were hetero-epitaxially grown on $SrTiO_3$ substrate with a various orientation by pulse laser deposition. $BiFeO_3$ films grown on (111) $SrTiO_3$ substrate have a rhombohedral structure, identical to that of single crystals. On the other hand, films grown on (110) or (001) $SrTiO_3$ substrate are monoclinically distorted from the rhombohedral structure due to the epitaxial constraint. The easy axis of spontaneous polarization is close to [111] for the variously oriented films. Dramatically enhanced polarization and magnetization have been found for $BiFeO_3$ thin films grown on $SrTiO_3$ substrate comparing to that of $BiFeO_3$ crystals. The results are explained in terms of an epitaxially-induced transition between cycloidal and homogeneous spin states, via magneto-electric interactions.