고성능 슈퍼커패시터 전극재료로서 극 교차 결합된 p-xylene 다공성 탄소 합성에 관한 연구 = Novel porous carbon material derived from hypercross-linked polymer of p-xylene for supercapacitors electrode

국문 초록 (Abstract)

본 학위 논문에서는 고성능 슈퍼커패시터 전극재료를 위한 Fridel-Crafts 알킬화 후 탄화를 통해 p-xylene 극 교차결합으로부터 유도된 높은 다공성을 가진 탄소 합성을 처음으로 보고한다. P-xylene 에서의 극 교차결합의 형성은 푸리에 변환 적외선(FT-IR) 분광법에 의해 확인되었다. 합성물질인 극 교차결합된 p-xylene(Hypercross-linked p-xylene, HCP-pXy) 및 열분해된 HCP-pXy(HCP-pXy-800)는 주사 전자 현미경(SEM), 투과 전자 현미경(TEM), 질소 흡착 등온선 및 분말 x-ray 회절 패턴 분석(XRD)에 의해 연구되었다. 3전극 시스템에서 HCP-pXy-800 전극은 3M KOH 수성 전해질 내 1.25Ag-1 전류 밀도에서 242.5Fg-1의 비정전용량을 나타냈다. 또한, 해당 전극은 1.25Ag-1의 전류밀도에서 2000번의 충방전 사이클 이후에도 95.18%의 비정전용량을 유지하여 그 다공성 탄소 전극의 우수한 충방전 사이클 안정성을 보여준다.

목차 (Table of Contents)

• 1. 서론 1
• 2. 이론적 배경 4
• 2.1 서론 4
• 2.2 슈퍼커패시터 전극재료 10
• 2.2.1 탄소재료 10
• 2.2.2 전도성 폴리머 재료 12
• 2.2.3 다공성 재료 14
• 2.2.4 다공성 폴리머 15
• 2.2.5 극교차 결합된 폴리머 15
• 2.2.6 산화금속재료 16
• 2.3 에너지 저장장치 전극재료 특성연구를 위한 기술들 17
• 2.3.1 순환 전압전류법 17
• 2.3.2 정전류 충-방전 실험 18
• 2.3.3 전기화학적 임피던스 분광법 19
• 3. 슈퍼커패시터 시장의 최근 동향과 그 다양한 활용 33
• 3.1 글로벌 슈퍼커패시터 시장의 성장 33
• 3.2 대표적인 슈퍼커패시터 제조사 33
• 3.2 슈퍼커패시터의 다양한 활용분야 36
• 4. 고성능 슈퍼커패시터 전극재료로서 hypercross-linked p-xylene 기반 다공성 탄소소재에 관한 연구 46
• 4.1 서론 46
• 4.2 실험과정 47
• 4.2.1 실험재료 47
• 4.2.2 p-xylene의 hypercross link 고분자 합성 47
• 4.2.3 HCP-pXy 재료의 Carbonization(탄화) 47
• 4.2.4 물리화학적 특성화 49
• 4.2.5 전기화학적 분석을 위한 전극제작 49
• 4.3 결과 및 논의 51
• 5. 결론 59
• 5.1 요약 59
• 5.2 향후 연구방향 59

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