<P>Using near-IR emitting photosensitizers, viz., zinc phthalocyanine (ZnPc), zinc naphthalocyanine (ZnNc), and BF<SUB>2</SUB>-chelated azadipyrromethene (azaBODIPY), donor–acceptor conjugates have been newly formed using the w...
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https://www.riss.kr/link?id=A107687955
2013
-
SCOPUS,SCIE
학술저널
5638-5649(12쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>Using near-IR emitting photosensitizers, viz., zinc phthalocyanine (ZnPc), zinc naphthalocyanine (ZnNc), and BF<SUB>2</SUB>-chelated azadipyrromethene (azaBODIPY), donor–acceptor conjugates have been newly formed using the w...
<P>Using near-IR emitting photosensitizers, viz., zinc phthalocyanine (ZnPc), zinc naphthalocyanine (ZnNc), and BF<SUB>2</SUB>-chelated azadipyrromethene (azaBODIPY), donor–acceptor conjugates have been newly formed using the well-known metal–ligand axial coordination approach. To accomplish this task, the electron-deficient azaBODIPY was functionalized to possess either two pyridine or imidazole ligating entities. The X-ray crystal structure of one such derivative revealed the presence of axial binding capable pyridine entities on the azaBODIPY macrocycle. The structural integrity of the newly formed conjugates was established from optical absorption, emission, <SUP>1</SUP>H NMR, electrochemical, and computational methods. The experimentally determined binding constants suggested moderately stable conjugates. The absence of excitation energy transfer from singlet excited azaBODIPY to either ZnPc or ZnNc in the conjugates was confirmed from the steady-state emission measurements. However, free-energy calculations suggested photoinduced electron transfer to be exothermic from singlet excited ZnPc or ZnNc to azaBODIPY. Femtosecond transient studies confirmed such predictions from where occurrence of ultrafast photoinduced electron transfer was observed. The measured rates of charge separation and charge recombination (<I>k</I><SUB>CS</SUB> and <I>k</I><SUB>CR</SUB>) revealed charge stabilization to some extent in these conjugates.</P><P><B>Graphic Abstract</B>
<IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jpccck/2013/jpccck.2013.117.issue-11/jp400046b/production/images/medium/jp-2013-00046b_0015.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/jp400046b'>ACS Electronic Supporting Info</A></P>
Visible-Light Response of 4-Aminobenzenethiol and 4,4′-Dimercaptoazobenzene Silver Salts