<P>Herein, we report a <I>de novo</I> synthesis approach to produce bandgap-controlled polyaniline (PAni) nanostructure <I>via</I> Mn-mediated oxidative polymerization at the catalytic nanoreactor. To achieve systemic nan...
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https://www.riss.kr/link?id=A107703518
2019
-
SCOPUS,SCIE
학술저널
2434-2438(5쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>Herein, we report a <I>de novo</I> synthesis approach to produce bandgap-controlled polyaniline (PAni) nanostructure <I>via</I> Mn-mediated oxidative polymerization at the catalytic nanoreactor. To achieve systemic nan...
<P>Herein, we report a <I>de novo</I> synthesis approach to produce bandgap-controlled polyaniline (PAni) nanostructure <I>via</I> Mn-mediated oxidative polymerization at the catalytic nanoreactor. To achieve systemic nanoconfined polymerization, manganese oxide (MnOx) nanoparticles coated with silica were used as the sacrificial nanotemplate. Interestingly, the catalytic nanoreactor simultaneously allowed the nanoconfined oxidative polymerization and controlling of the bandgap. MnOx could be reduced by the addition of aniline monomers and consecutive redox reaction at the nanoreactor. Furthermore, core cavity was generated, and ionized Mn could control the bandgap by coordination at the nanostructures.</P>