Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes

다국어 초록 (Multilingual Abstract)

Herein, we demonstrated a facile sonochemical preparation of manganese hexacyanoferrate (Mn-HCF) and examined its use as an intercalative-type electrode for Li-ion hybrid capacitors (LHCs). The X-ray diffraction, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopic analyses revealed the formation of Mn-HCF nanocubes. The electrochemical analyses revealed the presence of ion-intercalation pseudocapacitance in the Mn-HCF electrode with a specific capacity of 81.59 mAh g−1. In the view of practical applications, we designed a Mn-HCF∥graphene LHC which delivered a high specific capacitance (79.52 F g−1) and energy density (44.18 Wh kg−1), respectively. Overall, our results highlight the significance of Mn-HCF towards cost-effective energy storage devices.

참고문헌 (Reference)

1 M. Hook, 52 : 797-, 2013

2 W. Gao, 5 (5): 4144-, 2017

3 P.M. Shafi, 5 (5): 4757-, 2017

4 C. Zhou, 13 (13): 2078-, 2013

5 S. Vijayakumar, 238 : 99-, 2017

6 X. Lu, 25 (25): 267-, 2013

7 B. Zhao, 7 : 32-, 2017

8 Y. Wang, 45 (45): 5925-, 2016

9 K. Jeyasubramanian, 98 : 25-, 2018

10 P. Pazhamalai, 41 (41): 14830-, 2016

11 V.K. Mariappan, 265 : 514-, 2018

12 J. Feng, 133 (133): 17832-, 2011

13 A. Chaturvedi, 5 (5): 9177-, 2017

14 H. Wang, 2 (2): 3223-, 2014

15 K. Jeyasubramanian, 227 : 401-, 2017

16 H. Peng, 5 (5): 5951-, 2017

17 A. Pendashteh, 3 (3): 16849-, 2015

18 M. Pasta, 5 : 3007-, 2014

19 G.K. Veerasubramani, 147 (147): 836-, 2014

20 D. Mohapatra, 6 (6): 14720-, 2016

21 S. Nagamuthu, 199 : 543-, 2017

22 Z. Fan, 21 (21): 2366-, 2011

23 F. Wang, 46 (46): 6816-, 2017

24 K. Fic, 5 (5): 5842-, 2012

25 B. Xie, 9 (9): 5636-, 2015

26 J. Yan, 5 (5): 21404-, 2013

27 F.X. Wang, 246 : 19-, 2014

28 N. Wu, 8 (8): 25361-, 2016

29 C. Rong, 7 (7): 23104-, 2015

30 C. Zhong, 44 (44): 7484-, 2015

31 K. Krishnamoorthy, 4 (4): 3302-, 2017

32 S. Vijayan, 4 (4): 2059-, 2017

33 P. Sennu, 9 (9): 849-, 2016

34 C.D. Wessells, 159 (159): A98-, 2012

35 V. Aravindan, 114 (114): 11619-, 2014

36 C.D. Wessells, 2 : 550-, 2011

37 F. Zhao, 6 (6): 11007-, 2014

38 S. Liu, 3 (3): 959-, 2015

39 H. Pang, 7 (7): 16012-, 2015

40 K. Krishnamoorthy, 116 (116): 17280-, 2012

41 K. Krishnamoorthy, 5 (5): 5726-, 2017

42 K. Lu, 3 (3): 16013-, 2015

43 M. Pasta, 4 (4): 4211-, 2016

44 R. Agarwal, 1 (1): 3562-, 2016

45 X. Wang, 41 (41): 13540-, 2016

46 S.R. Marri, 53 (53): 228-, 2017

47 Y. Moritomo, 210 : 963-, 2016

48 H.-W. Lee, 5 : 5280-, 2014

49 R.B. Rakhi, 27 (27): 5314-, 2015

50 M.-X. Guo, 209 : 486-, 2016

51 P. Pachfule, 8 (8): 718-, 2016

52 Y. Wang, 6 (6): 6196-, 2014

53 S. Liu, 188 : 898-, 2016

54 J. Huang, 246 : 371-, 2014

55 R. Ding, 107 : 494-, 2013

56 K. Lu, 3 (3): 16013-, 2015

57 S.J. Patil, "Towards high performance unique microstructures of Co9S8//CoFe2O4 for asymmetric supercapacitor" 한국공업화학회 61 : 206-215, 2018

58 이민의, "High-performance Li-ion hybrid supercapacitors based on microporous pyropolymer nanoplates and orthorhombic Nb2O5 nanocomposites" 한국공업화학회 57 : 284-289, 2018

59 C.D. Lokhande, "High electrochemical performance asymmetric supercapacitor based on La2O3//Co3O4 electrodes" 한국공업화학회 56 : 90-98, 2017

60 Sanjit Saha, "Electrochemical functionalization and in-situ deposition of the SAA@rGO/h-BN@Ni electrode for supercapacitor applications" 한국공업화학회 52 : 321-330, 2017