<P>Reaction of a nonheme iron(<SMALL>III</SMALL>)-peroxo complex, [Fe<SUP>III</SUP>(14-TMC)(O<SUB>2</SUB>)]<SUP>+</SUP>, with NO<SUP>+</SUP>, a transformation which is essentially isoel...
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https://www.riss.kr/link?id=A107613480
2014
-
SCOPUS,SCIE
학술저널
1742-1744(3쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>Reaction of a nonheme iron(<SMALL>III</SMALL>)-peroxo complex, [Fe<SUP>III</SUP>(14-TMC)(O<SUB>2</SUB>)]<SUP>+</SUP>, with NO<SUP>+</SUP>, a transformation which is essentially isoel...
<P>Reaction of a nonheme iron(<SMALL>III</SMALL>)-peroxo complex, [Fe<SUP>III</SUP>(14-TMC)(O<SUB>2</SUB>)]<SUP>+</SUP>, with NO<SUP>+</SUP>, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(<SMALL>III</SMALL>)(O<SUB>2</SUB>&z.rad;<SUP>−</SUP>) + NO], affords an iron(<SMALL>IV</SMALL>)-oxo complex, [Fe<SUP>IV</SUP>(14-TMC)(O)]<SUP>2+</SUP>, and nitrogen dioxide (NO<SUB>2</SUB>), followed by conversion to an iron(<SMALL>III</SMALL>)-nitrato complex, [Fe<SUP>III</SUP>(14-TMC)(NO<SUB>3</SUB>)(F)]<SUP>+</SUP>.</P>
<P>Graphic Abstract</P><P>Reaction of a nonheme iron(<SMALL>III</SMALL>)-peroxo complex, [Fe<SUP>III</SUP>(14-TMC)(O<SUB>2</SUB>)]<SUP>+</SUP>, with NO<SUP>+</SUP> affords an iron(<SMALL>IV</SMALL>)-oxo complex, [Fe<SUP>IV</SUP>(14-TMC)(O)]<SUP>2+</SUP>, and nitrogen dioxide (NO<SUB>2</SUB>), followed by conversion to the nitrato complex, [Fe<SUP>III</SUP>(14-TMC)(NO<SUB>3</SUB>)(F)]<SUP>+</SUP>.
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