중.저준위 방사성 폐기물 처분부지의 지구화학 특성 I. 지하수 = Geochemical characteristics of a LILW repository I. Groundwater

다국어 초록 (Multilingual Abstract)

This study was carried out to identify the characteristics of hydrochemistry controlling groundwater chemical condition in a repository site of Gyeongju. For this study, 12 bore holes of all monitoring bore holes in the study area were selected and total 46 groundwater samples were collected with depth. In addition, 3 surfacewater samples and 1 seawater sample were collected. For water samples, cations and anions were analyzed. The environmental isotopes(${\delta}^{18}O-{\delta}D$, Tritium, ${\delta}^{13}C,\;{\cdot}{\delta}^{34}S$) were also analyzed to trace the origin of water and solutes. The result of ${\delta}^{18}O\;and\;{\delta}D$ analysis showed that surface water and groundwater were originated from precipitation. Tritium concentrations of groundwater decreased with depth but high concentrations of tritium indicated that groundwater was recharged recently. The results of ion and correlation analysis showed that groundwater types of the study area were represented by Ca-Na-$HCO_3$ and Na-Cl-$SO_4$, which was caused by sea spray and water-rock interaction. Especially, high ratio of Na content in groundwater resulted from ion exchange. For redox condition of groundwater, the values of DO and Eh decreased with depth, which indicated that reducing condition was formed in deeper groundwater. In addtion, high concentration of Fe and Mn showed that redox condition of groundwater was controlled by the reduction of Fe and Mn oxides.