<P><B>Abstract</B></P> <P>Supercapacitors based on nanomaterial electrodes exhibit great potential as power sources for advanced electronic devices. From a practical viewpoint, it is desirable to fabricate highly active ...
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https://www.riss.kr/link?id=A107522628
2018
-
SCI,SCIE,SCOPUS
학술저널
782-788(7쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>Supercapacitors based on nanomaterial electrodes exhibit great potential as power sources for advanced electronic devices. From a practical viewpoint, it is desirable to fabricate highly active ...
<P><B>Abstract</B></P> <P>Supercapacitors based on nanomaterial electrodes exhibit great potential as power sources for advanced electronic devices. From a practical viewpoint, it is desirable to fabricate highly active and sustainable nanomaterial electrodes consisting of non-precious elements using a simple technique in a controllable way. In this work, we report the synthesis of a self-assembled ultra-thin porous nanoflake Ni-Mo oxide (NMO) film using the successive ionic layer adsorption and reaction (SILAR) technique. The nanoflake NMO thin film electrode with a large electrochemically active surface area of ∼108 cm<SUP>−2</SUP> exhibits a high specific capacitance of 1180 Fg<SUP>−1</SUP> at a current density of 1 Ag<SUP>−1</SUP> and excellent rate capability, with a negligible capacity loss of 0.075% per cycle. Even at a high current rate of 10 A g<SUP>−1</SUP> it retains a capacity of 600 Fg<SUP>−1</SUP>. The highest energy and power densities obtained are 119 Whkg<SUP>−1</SUP> and 15.7 kWkg<SUP>−1</SUP>, respectively. Electrochemical impedance spectroscopy analyses reveal that the electrode has considerably low charge transfer resistance. The observed excellent electrochemical energy storage performance of the nanoflake NMO electrode with a nanoporous surface is due to the synergetic effects of the large electrochemically active surface area, enhanced ion diffusion, and improved electrical conductivity.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Ultra-thin porous Ni-Mo oxide nanoflakes self-assemble on stainless steel via a SILAR method. </LI> <LI> Large electrochemically-active surface area, enhanced ion diffusion and robust adhesion result in superior performance. </LI> <LI> High specific capacitance of 1180 F/g and energy density of 119 Wh/kg at 1 A/g are achieved. </LI> </UL> </P>
15-Mode piezoelectric composite and its application in a magnetoelectric laminate structure